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American Mineralogist

Journal of Earth and Planetary Materials

Ed. by Putirka, Keith / Swainson, Ian

12 Issues per year


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1945-3027
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Volume 94, Issue 2-3 (Feb 2009)

Issues

Suhailite, a new ammonium trioctahedral mica

María Dolores Ruiz Cruz
  • Corresponding author
  • Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga, Spain
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/ Carlos Sanz de Galdeano
Published Online: 2015-04-01 | DOI: https://doi.org/10.2138/am.2009.3008

Abstract

A new ammonium-bearing trioctahedral mica (suhailite) has been found in gneisses from the Betic Cordillera (Spain). Suhailite appears as aggregates of golden grains unoriented with respect to the main foliation. It shows weak pleochroism from light to darker yellow and low birefringence (0.028). X-ray data indicate the presence of two compositional variations: a NH4-rich phase (with a basal spacing of 10.40-10.44 Å) and a NH4-K intermediate phase (with basal spacing of 10.20-10.26 Å). Average composition, as deduced from analyses obtained at the scale of the scanning electron microscope is [Ca0.04Na0.07K0.35(NH4)0.55](Al0.42Ti0.22Fe1.33Mn0.01Mg0.71)Σ=2.70(Si2.67Al1.33)O10(OH)2. Thermal data indicate that maximum NH4 detachment occurs at 502 °C, suggesting a thermal stability similar to tobelite. Textural data indicate that unoriented golden grains consist of fine intergrowths of annite and suhailite and suggest that suhailite formed from primary red annite during the annite to fibrolite transformation.

Keywords : Annite; Betic Cordillera; suhailite; SEM; TEM/AEM; XRD

About the article

Received: 2008-04-25

Accepted: 2008-09-16

Published Online: 2015-04-01

Published in Print: 2009-02-01


Citation Information: American Mineralogist, ISSN (Online) 1945-3027, ISSN (Print) 0003-004X, DOI: https://doi.org/10.2138/am.2009.3008.

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