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American Mineralogist

Journal of Earth and Planetary Materials

Ed. by Putirka, Keith / Swainson, Ian

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IMPACT FACTOR 2016: 2.021

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Volume 101, Issue 12 (Dec 2016)

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High-pressure compressibility and vibrational properties of (Ca,Mn)CO3

Jin Liu
  • Department of Geological Sciences, Stanford University, Stanford, California 94305, United States of America
  • Email:
/ Razvan Caracas
  • CNRS, Laboratoire de Géologie de Lyon, Université Claude Bernard Lyon 1, 69342 Lyon Cedex 07, France
/ Dawei Fan
  • Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou 550002, China
/ Ema Bobocioiu
  • CNRS, Laboratoire de Géologie de Lyon, Université Claude Bernard Lyon 1, 69342 Lyon Cedex 07, France
/ Dongzhou Zhang
  • Hawai’i Institute of Geophysics and Planetology, University of Hawai’i at Manoa, Honolulu, Hawaii 96822, United States of America
/ Wendy L. Mao
  • Department of Geological Sciences, Stanford University, Stanford, California 94305, United States of America
  • Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States of America
Published Online: 2016-11-30 | DOI: https://doi.org/10.2138/am-2016-5742

Abstract

Knowledge of potential carbon carriers such as carbonates is critical for our understanding of the deep-carbon cycle and related geological processes within the planet. Here we investigated the high-pressure behavior of (Ca,Mn)CO3 up to 75 GPa by synchrotron single-crystal X-ray diffraction, laser Raman spectroscopy, and theoretical calculations. MnCO3-rich carbonate underwent a structural phase transition from the CaCO3-I structure into the CaCO3-VI structure at 45–48 GPa, while CaCO3-rich carbonate transformed into CaCO3-III and CaCO3-VI at approximately 2 and 15 GPa, respectively. The equation of state and vibrational properties of MnCO3-rich and CaCO3-rich carbonates changed dramatically across the phase transition. The CaCO3-VI-structured CaCO3-rich and MnCO3-rich carbonates were stable at room temperature up to at least 53 and 75 GPa, respectively. The addition of smaller cations (e.g., Mn2+, Mg2+, and Fe2+) can enlarge the stability field of the CaCO3-I phase as well as increase the pressure of the structural transition into the CaCO3-VI phase.

Key words: Carbonate; X-ray diffraction; raman spectroscopy; high pressure

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About the article

Received: 2016-02-27

Accepted: 2016-07-25

Published Online: 2016-11-30

Published in Print: 2016-12-01



Citation Information: American Mineralogist, ISSN (Online) 1945-3027, ISSN (Print) 0003-004X, DOI: https://doi.org/10.2138/am-2016-5742. Export Citation

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