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American Mineralogist

Journal of Earth and Planetary Materials

Ed. by Baker, Don / Xu, Hongwu / Swainson, Ian


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Volume 102, Issue 10

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Biologically mediated crystallization of buddingtonite in the Paleoproterozoic: Organic-igneous interactions from the Volyn pegmatite, Ukraine

Gerhard Franz
  • Corresponding author
  • Fachgebiet Mineralogie-Petrologie, Technische Universität Berlin, Ackerstr. 76, D-13355 Berlin, FR Germany
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/ Vladimir Khomenko
  • The National Academy of Sciences, Semenenko Institute of Geochemistry, Mineralogy and Ore Formation, 34, Palladina av., Kyiv-142, 03680, Ukraine
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/ Aleksei Vishnyevskyy
  • The National Academy of Sciences, Semenenko Institute of Geochemistry, Mineralogy and Ore Formation, 34, Palladina av., Kyiv-142, 03680, Ukraine
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/ Richard Wirth
  • Helmholtz Centre Potsdam, GFZ German Research Centre for Geosciences, Sektion 3.1, Telegrafenberg, D-14473 Potsdam, Germany
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/ Ulrich Struck
  • Museum für Naturkunde, Leibniz-Institut für Evolutions-und Biodiversitätsforschung, Invalidenstrasse 43, D-10115 Berlin, Germany
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/ Jörg Nissen
  • ZE Elektronenmikroskopie, Technische Universität Berlin, Strasse des 17, Juni 135, D-10623 Berlin, Germany
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/ Ulrich Gernert
  • ZE Elektronenmikroskopie, Technische Universität Berlin, Strasse des 17, Juni 135, D-10623 Berlin, Germany
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/ Alexander Rocholl
  • Helmholtz Centre Potsdam, GFZ German Research Centre for Geosciences, Sektion 3.1, Telegrafenberg, D-14473 Potsdam, Germany
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Published Online: 2017-10-02 | DOI: https://doi.org/10.2138/am-2017-6055

Abstract

The Volyn pegmatites from Volodarsk-Volynskyi in the Zhytomyr Oblast, NW Ukraine, are associated with granites genetically related to the Paleoproterozoic Korosten pluton. Their late-stage evolution is characterized by the formation of opal-cemented breccia. A polymineralic pseudomorph after beryl within the breccia includes bertrandite (±euclase) + F-muscovite (with tobelite component) + buddingtonite + organic matter (OM) + opal (+ traces of K-feldspar, albite, columbite, FeS2, barite, REE-minerals). Sector-zoned and platy to fibrous buddingtonite has variable (K+Na)-vs. NH4,-contents (electron microprobe analyses) and some H2O or H3O+, as indicated by microscope infrared spectroscopy. We suggest that ammonium was produced by decay of OM, which is partly preserved in the pseudomorph. Energy-dispersive electron microprobe data of the OM show with increasing O–decreasing C-N-content due to degassing; the OM contains the high field strength elements Zr (≤7 at%), Y (≤3 at%), Sc (≤0.8 at%), REE (≤0.3 at%), Th (≤0.2 at%), and U (≤1.25 at%), which increase with increasing O-content. Transmission electron microscopy of the OM confirms the presence of N; Zr, Si, and O (with other HFSE) are concentrated in nanometer-sized areas and at the transition from OM to opal in nanometer-sized platy Zr-Si-O crystals. C-rich areas are amorphous but show poorly developed lattice fringes. OM is present in the pseudomorph also as brown pigmentation of opal and in pegmatitic beryl from Volyn as a component in late stage fluid inclusions, identified by C-H vibrational bands in infrared spectra. Stable isotope investigations of C and N of buddingtonite, black opal and kerite (fibrous OM known from the literature to occur in the Volyn pegmatites and interpreted as microfossils) indicate a biogenic origin of the OM. We propose that OM in the pseudomorph is condensed kerite, which achieved the high concentrations of high field strength elements via fluid-pegmatite interaction. Although no age determination of minerals in the pseudomorph is available, textural arguments and phase equilibria indicate its formation in a late stage of the pegmatite evolution, at P-T conditions below ~100 MPa/150 °C. We favor a conceptual model for the formation of the Volyn buddingtonite in analogy to Phanerozoic occurrences of buddingtonite, where over and around the shallow anorthosite-granite Korosten pluton hydrothermal convection cells introduced N-bearing hydrocarbons and its precursors into the cooling igneous rocks. Due to the elevated temperature, the OM disintegrated into degassing volatile and non-volatile residual components analogous to petroleum maturation. Organic N, released as NH4, was then incorporated into buddingtonite.

Keywords: Buddingtonite; tobelite; kerite; organic matter; Volodarsk-Volynskyi pegmatite field

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About the article

Received: 2016-12-12

Accepted: 2017-06-07

Published Online: 2017-10-02

Published in Print: 2017-10-26


Citation Information: American Mineralogist, Volume 102, Issue 10, Pages 2119–2135, ISSN (Online) 1945-3027, ISSN (Print) 0003-004X, DOI: https://doi.org/10.2138/am-2017-6055.

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