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Autex Research Journal

The Journal of Association of Universities for Textiles (AUTEX)


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2300-0929
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Synthesis of Polymer Inclusion Membranes based on Cellulose Triacetate for Recovery of Lanthanum(III) from Aqueous Solutions

Adam Makowka
  • Department of Chemistry, Czestochowa University of Technology, Armii Krajowej 19, 42-200 Czestochowa, Poland
  • Other articles by this author:
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/ Beata Pospiech
  • Corresponding author
  • Department of Chemistry, Czestochowa University of Technology, Armii Krajowej 19, 42-200 Czestochowa, Poland
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Published Online: 2019-08-21 | DOI: https://doi.org/10.1515/aut-2018-0056

Abstract

Polymer inclusion membrane (PIM) containing cellulose triacetate (CTA) as a polymer matrix and 2-nitrophenyl octyl ether (NPOE) as a plasticizer was developed. This membrane also contained di(2-ethylhexyl)phosphoric acid (D2EHPA) and tributyl phosphate (TBP) as the carriers of metal ions. The facilitated transport of lanthanum(III) from aqueous nitrate(V) solutions across PIM was studied. It was observed that metal ions were transported from the source phase into 2M H2SO4 as the receiving phase. The transport through PIM with D2EHPA as the ion carrier was found as the more effective method of lanthanum(III) removal from the aqueous solution than transport through PIM with TBP as the ion carrier.

Keywords: polymer inclusion membrane (PIM); lanthanum(III); cerium(III); rare earth elements (REEs); di(2-ethylhexyl) phosphoric acid (D2EHPA); tributyl phosphate (TBP)

References

  • [1] Lister, T. E., Wang, P., Anderko, A. (2014). Recovery of critical and value metals from mobile electronic enabled by electrochemical processing. Hydrometallurgy 149, 228-237.Google Scholar

  • [2] Jha, M. K., Kumari, A., Panda, R., Kumar J. R., Yoo, K., Lee, J. Y. (2016). Review on hydrometallurgical recovery of rare earth metals. Hydrometallurgy 165, 2-26.Google Scholar

  • [3] Xie, F., Zhang, T. A., Dreisinger, D., Doyle, F. (2014). A critical review on solvent extraction of rare earths from aqueous solutions. Mineral Engineering, 56, 10-28.Google Scholar

  • [4] Kujawski, W., Pospiech, B. (2014). Process and technologies for the recycling of spent fluorescent lamps. Polish Journal of Chemical Technology, 16, 3, 80-85.Google Scholar

  • [5] Mishra, S., Sahu, S. K. (2016). Solvent extraction of Ce(III) from nitric acid medium using binary mixture of PC 88A and Cyanex 921. Hydrometallurgy 166, 252-259.Google Scholar

  • [6] Nasab, M. E., Sam, A., Milani, S. A. (2011). Determination of optimum process conditions for the separation of thorium and rare earth elements by solvent extraction. Hydrometallurgy 106, 141-147.Google Scholar

  • [7] Kumbasar, R. A., Tutkun, O. (2004). Separation and concentration of gallium from acidic leach solutions containing various metal ions by emulsion type of liquid membranes using TOPO as mobile carrier. Hydrometallurgy, 75, 111-121.Google Scholar

  • [8] Zhang, F., Wu, W., Bian, X., Zeng, W. (2014). Synergistic extraction and separation of lanthanum(III) and cerium(III) using a mixture of 2-ethylhexylphosphonic mono-2-ethylhexyl ester and di-2-ethylhexyl phosphoric acid in the presence of two complexing agents containing lactic acid and citric acid. Hydrometallurgy, 149, 238-24.Google Scholar

  • [9] Zhao, Z., Qiu, Z., Yang, J., Lu, S., Cao, L., Zhang, W., Xu, Y. (2017). Recovery of rare earth elements from spent fluid catalytic cracking catalysts using leaching and solvent extraction techniques. Hydrometallurgy 167, 183-188.Google Scholar

  • [10] Ines, M., Almeida, G. S., Cattrall, R. W., Kolev, S. D. (2012). Recent trends in extraction and transport of metal ions using polymer inclusion membranes (PIMs). Journal of Membrane Science, 415-416, 9-23.Google Scholar

  • [11] Kaya, A., Onac, C., Surucu, A., Karapinar, E., Alpoguz, H. K., Tabaki, E. (2014). Preparation of CTA-based polymer inclusion membrane using calix[4]arene derivative as a carrier for Cr(VI) transport. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 79, 103-111.Google Scholar

  • [12] Pospiech, B., Kujawski, W. (2015). Ionic liquids as selective extractants and ion carriers of heavy metal ions from aqueous solutions utilized in extraction and membrane separation. Reviews in Chemical Engineering 31, 179-191.Google Scholar

  • [13] Kusumocahyo, S. P., Kanamori, T., Sumaru, K., Aomatsu, S., Matsuyama, H., Teramoto, M., Shinbo, T. (2004). Development of polymer inclusion membranes based on cellulose triacetate: carrier-mediated transport of cerium(III). Journal of Membrane Science 244, 251-257.Google Scholar

  • [14] Pospiech, B. (2015). Studies on extraction and permeation of cadmium(II) using Cyphos IL 104 as selective extractant and ion carrier. Hydrometallurgy, 154, 88-94.Google Scholar

  • [15] Pospiech, B. (2018). Facilitated transport of palladium(II) across polymer inclusion membranes with ammonium ionic liquid as effective carrier. Chemical Papers, 72(2), 301-308.Google Scholar

About the article

Published Online: 2019-08-21

Published in Print: 2019-09-01


Citation Information: Autex Research Journal, Volume 19, Issue 3, Pages 288–292, ISSN (Online) 2300-0929, DOI: https://doi.org/10.1515/aut-2018-0056.

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© 2019 Adam Makowka et al., published by Sciendo. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License. BY-NC-ND 4.0

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