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Civil and Environmental Engineering Reports

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Adsorption of Polycyclic Aromatic Hydrocarbons (PAHS) from Aqueous Solutions on Different Sorbents

Marzena Smol / Maria Włodarczyk-Makuła / Dariusz Włóka
Published Online: 2014-12-10 | DOI: https://doi.org/10.2478/ceer-2014-0017

Abstract

This paper presents the results of the possibility and effectiveness of PAHs removal from a model aqueous solution, during the sorption on the selected sorbents. Six PAHs (naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene) listed by EPA for the analysis in the environmental samples were determined. Model aqueous solution was prepared with RESTEK 610 mix PAHs standard. After the sorption process, decrease in the concentration of individual hydrocarbons was observed. The removal percentage was dependent on the type of sorbent (quartz sand, mineral sorbent, activated carbon). The highest efficiency (98.1%) was observed for activated carbon.. The results shows that the sorption processes can be used in aqueous solutions treatment procedures.

Keywords: 2- and 3-rings of PAHs; adsorption; quartz sand; mineral sorbent; activated carbon

References

  • 1. Jones K.C. and De Voogt P.: Persistent organic pollutants (POPs): state of the science, Environmental Pollution 100.1 (1999) 209-221.CrossrefGoogle Scholar

  • 2. Gajewska M., Kopeć Ł. and Obarska-Pempkowiak H.: Operation of Small Wastewater Treatment facilities in a Scattered Settlement. Rocznik Ochrona Środowiska (Annual Set the Environment Protection), 13, I (2011) 207-225.Google Scholar

  • 3. Włodarczyk-Makuła M.: Behaviour of PAHs during sewage sludge fermentation in the presence of sulphate and nitrate, Desalination and Water Treatment, 33(1-3) (2011) 178-184.CrossrefWeb of ScienceGoogle Scholar

  • 4. Kowal A.L. and Świderska - Bróż M.: Water treatment. Theoretical background and technological processes and devices, Polish Scientific Publishers, Warszawa, 2007. (in polish).Google Scholar

  • 5. Oleszczuk P.: Organic Pollutats in sewage sludge-amended soil part II. Fate of contaminants soils, Ecological Chemistry and Engineering, 14(S2) (2007)185-198.Google Scholar

  • 6. Xu Z.R., Zhu W., Li M., Zhang H.W. and Gong M.: Quantitative analysis of polycyclic aromatic hydrocarbons in solid residues from supercritical water gasification of wet sewage sludge, Applied Energy, 102, (2013) 476-483.Web of ScienceCrossrefGoogle Scholar

  • 7. Wolska L.: Determination (monitoring) of PAHs in surface waters: why an operationally defined procedure is needed, Analytical and Bioanalytical Chemistry, 39 (208) 2647-2652.Web of ScienceGoogle Scholar

  • 8. Hall s., Tang R., Baeyens J. and Dewil R.: Removing polycyclic aromatic hydrocarbons from water by adsorption on silicagel, Polycyclic Aromatic Compounds, 29(3) (2009) 160-183.CrossrefGoogle Scholar

  • 9. Lach J., Okoniewska E., Neczaj E. and Kacprzak M.: The adsorption of Cr (III) and Cr (VI) on activated carbons in the presence of phenol, Desalination, 223(1) (2008) 249-255.Google Scholar

  • 10. Pranagal J. and Oleszczuk P.: Thepolycyclic aromatic hydrocarbons content in selected silty soils. Archiwum Ochrony Środowiska, 32, (2006) 69-80.Google Scholar

  • 11. Caban-Pabian B. Studies on self-purification of mining waters contaminated with polycyclic aromatic hydrocarbons, Archives of Environmental Protection, 28 (2008) 57-66.Google Scholar

  • 12. Kaleta J.: Removal of chosen organic pollutions from aqueous solutions in sorption process, Scientific Papers of Rzeszów University of Technology Civil and Environmental Engineering, 43 (241) (2007) 17-30 (in polish).Google Scholar

  • 13. Dąbek L. and Ozimina E.: Oxidation of organic contaminants adsorbed on activated carbons, Environmental Protection and Natural Resources, 41 (2009) 427-436.Google Scholar

  • 14. Valderrama C., Gamisans X., Cortina J.L., Farrran A. and De Las Heras F.X.: Evaluation of polyaromatic hydrocarbon removal from aqueous solutions using activated carbon and hyper-crosslinked polymer (Macronet MN200), Journal of Chemical Technology and Biotechnology, 84 (2009) 236—245.Web of ScienceGoogle Scholar

  • 15. Ksycińska-Rębiś E., Lach J. and Okoniewska E.: The influence of carbon modification on the mechanism of phenol adsorption, Scientifical-Technical Conference: Activated carbon in environmental protection and industry, Częstochowa (2006) 160-168 (in polish).Google Scholar

  • 16. Chang C.F., Chang C.Y., Höll W., Ulmer M., Chen Y.H. and Groß H.J.: Adsorption kinetics of polyethylene glycol from aqueous solution onto activated carbon. Water Research, 38(10) (2004) 2559-2570.CrossrefGoogle Scholar

  • 17. Müller S., Totsche K. and Kögel - Knabner I.: Sorption of polycyclic aromatic hydrocarbons to mineral surfaces, European Journal of Soil Science, 58(4) (2007) 918-931.CrossrefWeb of ScienceGoogle Scholar

  • 18. Su Y.H., Zhu Y.G., Sheng G. and Chiou C.T.: Linear adsorption of nonionic organic compounds from water onto hydrophilic minerals: silica and alumina. Environmental science & technology, 40(22) (2006) 6949-6954.Google Scholar

  • 19. Li Y., Chen B., and Zhu L.: Enhanced sorption of polycyclic aromatic hydrocarbons from aqueous solution by modified pine bark, Bioresource technology, 101(19) (2010) 7307-7313.Web of ScienceCrossrefGoogle Scholar

  • 20. Pérez-Gregorio M.R., García-Falcón M.S., Martínez-Carballo E. and Simal-Gándara J.: Removal of polycyclic aromatic hydrocarbons from organic solvents by ashes wastes. Journal of hazardous materials, 178(1) (2010) 273281.Google Scholar

  • 21. Ali I. and Gupta V.K.: Advances in water treatment by adsorption technology, Nature Protocols, 1(6) (2007) 2661-2667.CrossrefGoogle Scholar

  • 22. Macherzyński B. and Włodarczyk-Makuła M.: Extraction of PAH from Sewage Sludge from Coke Wastewater Separated, Inżynieria i Ochrona Środowiska, 4(14) (2011) 333-343 (in polish).Google Scholar

  • 23. Repelewicz M., Jedynak K. and Choma J.: Struktura porowata i chemia powierzchni węgli aktywnych modyfikowanych kwasami nieorganicznymi. Environmental Pollution Control, 3(31) (2009) 45-50 (in polish).Google Scholar

  • 24. Choma J, Jaroniec M., Burakiewicz-Mortka W. and Gwizdalski M.: Adsorption of Organic Compounds from Aqueous Solutions on Activated Carbon, Environmental Pollution Control, 1(56) (1995) 11-17.Google Scholar

  • 25. Smol M. and Włodarczyk-Makuła M.: Effectiveness in the removal of Polycyclic Aromatic Hydrocarbons from industrial wastewater by ultrafiltration technique, Archives of Environmental Protection, 38(4) (2012) 49-58.Web of ScienceGoogle Scholar

  • 26. Włóka D., Kacprzak M., Rosikoń K. and Fijałkowski K.: Study of the migration of polycyclic aromatic hydrocarbons (PAH’s) in the sewage sludge-soil system, Environment Protection Engineering, 39(2) (2013) 113122.Google Scholar

About the article

* Częstochowa University of Technology, Institute of Environmental Engineering, ul. Brzeźnicka 60a, 42-200 Częstochowa, Poland; tel. +48343250919


Published Online: 2014-12-10


Citation Information: Civil And Environmental Engineering Reports, ISSN (Online) 2450-8594, ISSN (Print) 2080-5187, DOI: https://doi.org/10.2478/ceer-2014-0017.

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© 2014 Marzena Smol et. al.. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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