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Open Chemistry

formerly Central European Journal of Chemistry

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Influence of surfactants on the fading of malachite green

Adina Raducan
  • Dept. of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bulevardul Regina Elisabeta 4-12, Bucharest, 030018, Romania
  • :
/ Alexandra Olteanu
  • Dept. of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bulevardul Regina Elisabeta 4-12, Bucharest, 030018, Romania
  • :
/ Mihaela Puiu
  • Dept. of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bulevardul Regina Elisabeta 4-12, Bucharest, 030018, Romania
  • :
/ Dumitru Oancea
  • Dept. of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bulevardul Regina Elisabeta 4-12, Bucharest, 030018, Romania
  • :
Published Online: 2008-03-01 | DOI: https://doi.org/10.2478/s11532-007-0066-0

Abstract

The kinetics of the reaction between malachite green (MG) and sodium hydroxide (MG fading) was studied using a spectrophotometric method in the presence of two cationic surfactants, cetyl-benzyl-dimethyl-ammonium chloride (CBDAC) and hexadecyl-trimethylammonium bromide (HTAB) and one anionic surfactant, sodium dodecyl sulphate (SDS) at concentrations below and above critical micellar concentrations. The cationic surfactants have a catalytic effect, while the anionic surfactant has an inhibitory effect on the reaction. A kinetic model describing the influence of surfactant on reaction rate was developed. The results are discussed on the basis of electrostatic and hydrophobic interactions between the kinetic micelles and malachite green.

Keywords: Micellar catalysis; Malachite green fading; Kinetic micelles

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Published Online: 2008-03-01

Published in Print: 2008-03-01


Citation Information: Open Chemistry. Volume 6, Issue 1, Pages 89–92, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-007-0066-0, March 2008

© 2008 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. (CC BY-NC-ND 3.0)

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