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Open Chemistry

formerly Central European Journal of Chemistry

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IMPACT FACTOR 2016 (Open Chemistry): 1.027
IMPACT FACTOR 2016 (Central European Journal of Chemistry): 1.460

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Volume 6, Issue 3

Issues

Volume 13 (2015)

Palladium(0)-catalyzed amination of allylic natural terpenic functionalized olefins

Soufiane Houssame
  • Laboratoire de Chimie de Coordination, Faculté des Sciences-Semlalia, Université Cadi Ayyad, BP 2390, Marrakech, Morocco
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/ Hafid Anane
  • Département Sciences de la matière, Faculté Polydisciplinaire de Safi, Route Sidi bouzid, B.P 4162, Safi Université Cadi Ayyad, Morocco
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/ Larbi Firdoussi
  • Laboratoire de Chimie de Coordination, Faculté des Sciences-Semlalia, Université Cadi Ayyad, BP 2390, Marrakech, Morocco
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/ Abdellah Karim
  • Laboratoire de Chimie de Coordination, Faculté des Sciences-Semlalia, Université Cadi Ayyad, BP 2390, Marrakech, Morocco
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Published Online: 2008-08-11 | DOI: https://doi.org/10.2478/s11532-008-0042-3

Abstract

The palladium(0) catalyzed amination of allylic acetates and carbonates derivatives from terpenic olefins was carried out under mild conditions. The reaction offers a very good method for the preparation of allylic amines and thus to provide a useful entry to new functionalized terpenic olefin products. The mechanism involving a formation of p-allyl-palladium intermediate complex is in good agreement with the results obtained with the optically active substrates, as well as via an analysis of the observed regio-and stereoselectivity.

Keywords: Palladium; Allylic amination; Allylic functionalized terpenic olefin

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About the article

Published Online: 2008-08-11

Published in Print: 2008-09-01


Citation Information: Open Chemistry, Volume 6, Issue 3, Pages 470–476, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-008-0042-3.

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© 2008 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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