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Open Chemistry

formerly Central European Journal of Chemistry


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Volume 7, Issue 3

Issues

Volume 13 (2015)

A hydroxyaminophosphane derived from 2-imidazolidone and its unusual structure in solution

Olaf Kühl / Waltraud Heiden
Published Online: 2009-06-21 | DOI: https://doi.org/10.2478/s11532-009-0021-3

Abstract

A novel hydroxyamino phosphane was synthesised through the reaction of 2-imidazolidinone with ClPPh2 and subsequently reaction of the resulting bisphosphino derivative with the Grignard reagent BrMgC5H11. The interaction of the pentyl substituent with one of the two phosphino groups and the structure in solution is shown by multinuclear NMR-spectroscopy..

Keywords: Grignard reaction; Hydroxyaminophosphane; Phosphane; Reduction; „Through-space”-coupling

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About the article

Published Online: 2009-06-21

Published in Print: 2009-09-01


Citation Information: Open Chemistry, Volume 7, Issue 3, Pages 281–284, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-009-0021-3.

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© 2009 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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