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Open Chemistry

formerly Central European Journal of Chemistry


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Volume 7, Issue 3

Issues

Volume 13 (2015)

Heterogeneous catalytic ignition of n-butane/air mixtures on platinum

Octavian Staicu
  • Department of Physical Chemistry, University of Bucharest, 030018, Bucharest, Romania
  • “Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, 060021, Bucharest, Romania
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/ Domnina Razus / Valentin Munteanu / Dumitru Oancea
Published Online: 2009-06-21 | DOI: https://doi.org/10.2478/s11532-009-0040-0

Abstract

The heterogeneous catalytic ignition of lean to stoichiometric n-butane/air mixtures were studied at various total pressures between 10 and 100 kPa and at temperatures equal to or larger than the critical ignition temperatures. The induction periods, ignition and extinction temperatures were measured under strict isothermal conditions. The discussion presented in this paper is based on several literature models. The data analysis allowed for the determination of the overall kinetic parameters. The rigorous isothermal conditions indicated that the extinction temperatures are lower than the ignition, a behavior different from the results obtained in stagnation-point flow reactors.

Keywords: Catalytic ignition; n-Butane; Platinum wire; Ignition delay; Bifurcation

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About the article

Published Online: 2009-06-21

Published in Print: 2009-09-01


Citation Information: Open Chemistry, Volume 7, Issue 3, Pages 478–485, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-009-0040-0.

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© 2009 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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