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Open Chemistry

formerly Central European Journal of Chemistry


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2391-5420
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Volume 7, Issue 3

Issues

Volume 13 (2015)

Determination of Alizarin Red S using a novel B-Z oscillation system catalyzed by a tetraazamacrocyclic complex

Gang Hu / Lulu Chen / Jinfeng Zhang / Panpan Chen / Wei Wang / Jimei Song / Lingguang Qiu / Juan Song / Lin Hu
Published Online: 2009-06-21 | DOI: https://doi.org/10.2478/s11532-009-0042-y

Abstract

A new and convenient method for the determination of Alizarin Red S by the perturbations caused by different amounts of Alizarin Red S on a novel B-Z oscillating system is proposed. This new type Belousov-Zhabotinskii involves a macrocyclic copper(II) complex [CuL](ClO4)2 as catalyst and malic acid as the substrate. The ligand L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene. It is found that the relationship between the change in the oscillation amplitude and the logarithm of the Alizarin Red S concentration in the range of 1.5 × 10−7 to 1 × 10−3 M fits a polynomial model: ΔA = 659 + 184.2 log [Alizarin Red S]+ 12.9 log2 [Alizarin Red S]. The RSD obtained with ten samples is 4.4%. The probable mechanism involving the perturbation of Alizarin Red S on the oscillating chemical system is also discussed.

Keywords: Kinetic determination; Alizarin Red S; Tetraazamacrocyclic complex; Belousov-Zhabotinskii reaction

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About the article

Published Online: 2009-06-21

Published in Print: 2009-09-01


Citation Information: Open Chemistry, Volume 7, Issue 3, Pages 291–297, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-009-0042-y.

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© 2009 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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