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Open Chemistry

formerly Central European Journal of Chemistry

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IMPACT FACTOR 2016 (Open Chemistry): 1.027
IMPACT FACTOR 2016 (Central European Journal of Chemistry): 1.460

CiteScore 2017: 1.45

SCImago Journal Rank (SJR) 2017: 0.349
Source Normalized Impact per Paper (SNIP) 2017: 0.812

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2391-5420
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Volume 8, Issue 3

Issues

Volume 13 (2015)

Equilibrium and kinetic study of the proton transfer reactions between nitroalkanes and strong organic bases — phosphazenes in tetrahydrofuran solvent

Iwona Binkowska / Włodzimierz Gałęzowski / Arnold Jarczewski
Published Online: 2010-04-25 | DOI: https://doi.org/10.2478/s11532-010-0044-9

Abstract

Proton transfer reactions rates between carbon acids 1-nitro-1-(4-nitrophenyl)ethane (NPNE), 2-methyl-1-nitro-1-(4-nitrophenyl)propane (MNPNP)) and phosphazenes (BEMP, BTPP, P1-t-Oct) in tetrahydrofuran have been measured, and the activation parameters were determined. The results are compared with those previously obtained for P1-t-Bu phosphazene, guanidines and amidines.

Keywords: Proton/deuteron transfer; Carbon acids; Phosphazene bases

  • [1] R. Schwesinger, J. Willaredt, H. Schlemper, M. Keller, D. Schmitt, H. Fritz, Chem. Ber. 127, 2435 (1994) http://dx.doi.org/10.1002/cber.19941271215CrossrefGoogle Scholar

  • [2] R. Schwesinger et al., Liebigs Ann. 1055 (1996) Google Scholar

  • [3] R. Schwesinger, Angew. Chem. 105, 1420 (1994) http://dx.doi.org/10.1002/ange.19931050940CrossrefGoogle Scholar

  • [4] R. Schwesinger, Chimia 39, 269 (1985) Google Scholar

  • [5] R. Schwesinger, Nachr. Chem. Tech. Lab. 38, 1214 (1990) Google Scholar

  • [6] L.A. Paquette, Encyclopedia of reagent for organic synthesis (John Wiley & Sons, Chichester, 1995) 6, 4110 Google Scholar

  • [7] R. Schwesinger, H. Schlemper, Angew. Chem., Int. Ed. Engl. 26, 1168 (1987) Google Scholar

  • [8] I. Kaljurand, T. Rodima, I. Leito, I. A. Koppel, R. Schwesinger, J. Org. Chem. 65, 6202 (2000) http://dx.doi.org/10.1021/jo005521jCrossrefGoogle Scholar

  • [9] I. Leito, T. Rodima, I.A. Koppel, R. Schwesinger, V.M. Vlasov, J. Org. Chem. 62, 8479 (1997) http://dx.doi.org/10.1021/jo9713013CrossrefGoogle Scholar

  • [10] I.A. Koppel et al., J. Phys. Chem. A 105, 9575 (2001) http://dx.doi.org/10.1021/jp012168sCrossrefGoogle Scholar

  • [11] Ż. Wisıocka, I. Nowak, A. Jarczewski, J. Mol. Struct. 788, 152 (2006) http://dx.doi.org/10.1016/j.molstruc.2005.11.031CrossrefGoogle Scholar

  • [12] W. Gaıęzowski, A. Jarczewski, J. Chem. Soc. Perkin Trans. II, 1647 (1989) Google Scholar

  • [13] W. Gaıęzowski, A. Jarczewski, Can. J. Chem. 68, 2242 (1990) http://dx.doi.org/10.1139/v90-345CrossrefGoogle Scholar

  • [14] W. Gaıęzowski, I. Grześkowiak, A. Jarczewski, J. Chem. Soc., Perkin Trans. 2, 1607 (1998) Google Scholar

  • [15] A. Jarczewski, C. D. Hubbard, J. Mol. Struct. 649, 287 (2003) http://dx.doi.org/10.1016/S0022-2860(03)00086-3CrossrefGoogle Scholar

  • [16] M. Fletschinger, B. Zipperer, H. Fritz, H. Prinzbach, Tetrahedron Lett. 28, 2517 (1987) http://dx.doi.org/10.1016/S0040-4039(00)95456-XCrossrefGoogle Scholar

  • [17] L. Melander, W.H. Saunders Jr., Reaction rates of isotopic molecules (John Wiley and Sons, NewYork, 1980) 287 Google Scholar

  • [18] G. Bergson, Chem. Scr. 8, 145 (1975) Google Scholar

  • [19] E.S. Lewis, L.H. Funderburk, J. Am. Chem. Soc. 89, 2322 (1967) http://dx.doi.org/10.1021/ja00986a013CrossrefGoogle Scholar

  • [20] E.S. Lewis, L.H. Funderburk, J. Am. Chem. Soc. 86, 2531 (1964) http://dx.doi.org/10.1021/ja01066a055CrossrefGoogle Scholar

  • [21] R.P. Bell, The Proton in Chemistry, 2nd edition (Chapman and Hall, London, 1973) Google Scholar

About the article

Published Online: 2010-04-25

Published in Print: 2010-06-01


Citation Information: Open Chemistry, Volume 8, Issue 3, Pages 582–586, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-010-0044-9.

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© 2010 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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