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formerly Central European Journal of Chemistry

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Volume 8, Issue 4 (Aug 2010)

Issues

Crystal structures and spectral properties of new Cd(II) and Hg(II) complexes of monensic acid with different coordination modes of the ligand

Juliana Ivanova
  • Medical Faculty, Sofia University, Sofia, 1164, Bulgaria
  • Email:
/ Ivayla Pantcheva
  • Faculty of Chemistry, Sofia University, Sofia, 1164, Bulgaria
  • Email:
/ Mariana Mitewa
  • Faculty of Chemistry, Sofia University, Sofia, 1164, Bulgaria
  • Email:
/ Svetlana Simova
  • Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Sofia, 1113, Bulgaria
  • Email:
/ Heike Mayer-Figge
  • Department of Analytical Chemistry, Ruhr-Universität Bochum, D-44780, Bochum, Germany
  • Email:
/ William Sheldrick
  • Department of Analytical Chemistry, Ruhr-Universität Bochum, D-44780, Bochum, Germany
  • Email:
Published Online: 2010-06-17 | DOI: https://doi.org/10.2478/s11532-010-0067-2

Abstract

The single crystal X-ray structures and the spectroscopic properties of complexes of monensic acid (C36H62O11·H2O) with toxic metal ions of Cd(II) and Hg(II) are discussed. The cadmium(II) complex (1) is of composition [Cd(C36H61O11)2(H2O)2] and crystallizes in the monoclinic system (space group P2(1), Z = 2) with a = 12.4090(8), b = 24.7688(16), c = 14.4358(11) Å, β = 91.979(7)°. Two ligand monoanions are bound in a bidentate coordination mode to Cd(II) via the carboxylate and the primary hydroxyl oxygens occupying the equatorial plane of the complex. The axial positions of the inner coordination sphere of Cd(II) are filled by two water molecules additionally engaged in intramolecular hydrogen bonds. The Hg(II) complex (2), [Hg(C36H60O11)(H2O)], crystallizes in the orthorhombic system (space group P2(1)2(1)2(1), Z = 4) with a = 12.7316(2), b = 16.4379(3), c = 18.7184(4) Å. The monensic acid reacts with Hg(II) in a tetradentate coordination manner via both oxygen atoms of the carboxylate function and oxygens of two hydroxyl groups. The twofold negative charge of the ligand is achieved by deprotonation of carboxylic and secondary hydroxyl groups located at the opposite ends of the molecule. Hg(II) is surrounded by five oxygen atoms in a distorted square pyramidal molecular geometry.

Keywords: Monovalent polyether ionophore; Heavy metal complexes

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About the article

Published Online: 2010-06-17

Published in Print: 2010-08-01


Citation Information: Open Chemistry, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-010-0067-2. Export Citation

© 2010 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. (CC BY-NC-ND 3.0)

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