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Open Chemistry

formerly Central European Journal of Chemistry

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2391-5420
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Volume 8, Issue 6 (Dec 2010)

Issues

Synthesis and characterization of a new hybrid TiO2/SiO2 filler for lithium conducting gel electrolytes

Mariusz Walkowiak
  • Institute of Non-Ferrous Metals Branch in Poznań Central Laboratory of Batteries and Cells, 61-362, Poznań, Poland
  • Email:
/ Monika Osińska
  • Institute of Non-Ferrous Metals Branch in Poznań Central Laboratory of Batteries and Cells, 61-362, Poznań, Poland
  • Email:
/ Teofil Jesionowski
  • Institute of Chemical Technology and Engineering, Poznań University of Technology, 60-965, Poznań, Poland
  • Email:
/ Katarzyna Siwińska-Stefańska
  • Institute of Chemical Technology and Engineering, Poznań University of Technology, 60-965, Poznań, Poland
  • Email:
Published Online: 2010-10-08 | DOI: https://doi.org/10.2478/s11532-010-0110-3

Abstract

This paper describes the synthesis and properties of a new type of ceramic fillers for composite polymer gel electrolytes. Hybrid TiO2-SiO2 ceramic powders have been obtained by co-precipitation from titanium(IV) sulfate solution using sodium silicate as the precipitating agent. The resulting submicron-size powders have been applied as fillers for composite polymer gel electrolytes for Li-ion batteries based on poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF/HFP) copolymeric membranes. The powders, dry membranes and gel electrolytes have been examined structurally and electrochemically, showing favorable properties in terms of electrolyte uptake and electrochemical characteristics in Li-ion cells.

Keywords: Li-ion battery; Polymer gel electrolyte; PVdF/HFP; Functionalized ceramic filler

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About the article

Published Online: 2010-10-08

Published in Print: 2010-12-01


Citation Information: Open Chemistry, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-010-0110-3. Export Citation

© 2010 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. (CC BY-NC-ND 3.0)

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