Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Open Chemistry

formerly Central European Journal of Chemistry

1 Issue per year


IMPACT FACTOR 2016 (Open Chemistry): 1.027
IMPACT FACTOR 2016 (Central European Journal of Chemistry): 1.460

CiteScore 2016: 0.61

SCImago Journal Rank (SJR) 2016: 0.288
Source Normalized Impact per Paper (SNIP) 2016: 0.735

Open Access
Online
ISSN
2391-5420
See all formats and pricing
More options …
Volume 9, Issue 5

Issues

Determination of submillimolar concentration of ferrate(VI) in alkaline solutions by amperometric titration

Dmitriy Golovko
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Virender Sharma / Olga. Pavlova
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Elena. Belyanovskaya
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Igor. Golovko
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Victoria. Suprunovich
  • Faculty of Inorganic Substances Technology, Ukraine State Chemical Technological University, 49005, Dniepropetrovsk, Ukraine
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Radek Zboril
Published Online: 2011-07-24 | DOI: https://doi.org/10.2478/s11532-011-0069-8

Abstract

A new amperometric titration method was developed for quantitative determination of ferrate(VI) (FeVIO42−) in the 7.06×10−5−5.73×10−3 M concentration range. Chromium(III) hydroxide solution was used as the titrant. The diffusion current (Id) had a linear relationship with the concentration of ferrate(VI) and slopes were dependent on the concentration of NaOH. The amperometric titration could detect a lower concentration of ferrate(VI) than could potentiometric and colorimetric titrations. The method was applied successfully to determine concentrations of ferrate(VI), generated electrochemically, in strong alkaline solutions.

Keywords: Ferrate; Amperometric Titration; Electrochemical Analysis; Diffusion current; Chromite

  • [1] C. He, X. Li, V.K. Sharma, S. Li, Environ. Sci. Technol. 43, 5890 (2009) http://dx.doi.org/10.1021/es900397yCrossrefGoogle Scholar

  • [2] C. Li, X.Z. Li, N. Graham, N.Y. Gao, Water Res. 42, 109 (2008) http://dx.doi.org/10.1016/j.watres.2007.07.023CrossrefGoogle Scholar

  • [3] C. Lee, Y. Lee, C. Schmidt, J. Yoon, U. von Gunten, Water Res. 42, 433 (2008) http://dx.doi.org/10.1016/j.watres.2007.07.035CrossrefGoogle Scholar

  • [4] J.Q. Jiang, Q. Yin, J.L. Zhou, P. Pearce, Chemosphere. 61, 544 (2005) http://dx.doi.org/10.1016/j.chemosphere.2005.02.029CrossrefGoogle Scholar

  • [5] V.K. Sharma, J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng. 45, 645 (2010) http://dx.doi.org/10.1080/10934521003648784CrossrefGoogle Scholar

  • [6] V.K. Sharma, Environ. Sci. Technol. 45, 5148 (2010) http://dx.doi.org/10.1021/es1005187CrossrefGoogle Scholar

  • [7] V.K. Sharma, F. Kazama, H. Jiangyong, A.K. Ray, J. Water Health. 3, 45 (2005) Google Scholar

  • [8] Y. Lee, U.V. Gunten, Water Res. 44, 555 (2010) http://dx.doi.org/10.1016/j.watres.2009.11.045CrossrefGoogle Scholar

  • [9] J.Q. Jiang, J. Hazard. Mater. 146, 617 (2007) http://dx.doi.org/10.1016/j.jhazmat.2007.04.075CrossrefGoogle Scholar

  • [10] V.K. Sharma, Chemosphere. 73, 1379 (2008) http://dx.doi.org/10.1016/j.chemosphere.2008.08.033CrossrefGoogle Scholar

  • [11] V.K. Sharma, R.A. Yngard, D.E. Cabelli, J. Clayton Baum, Radiat. Phys. Chem. 77, 761 (2008) http://dx.doi.org/10.1016/j.radphyschem.2007.11.004CrossrefGoogle Scholar

  • [12] V.K. Sharma, G.A.K. Anquandah, R.A. Yngard, H. Kim, J. Fekete, K. Bouzek, A.K. Ray, D. Golovko, J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng. 44, 423 (2009) http://dx.doi.org/10.1080/10934520902719704CrossrefGoogle Scholar

  • [13] V.K. Sharma, J. Environ. Manag. 92, 1051 (2011) http://dx.doi.org/10.1016/j.jenvman.2010.11.026CrossrefGoogle Scholar

  • [14] V.K. Sharma, G.W. Luther III, F.J. Millero, Chemosphere 82, 1083 (2011) http://dx.doi.org/10.1016/j.chemosphere.2010.12.053CrossrefGoogle Scholar

  • [15] Y. Lee, S.G. Zimmermann, A.T. Kieu, G.V. Gunten, Environ. Sci. Technol. 43, 3831 (2009) http://dx.doi.org/10.1021/es803588kCrossrefGoogle Scholar

  • [16] J.Q. Jiang, S. Wang, A. Panagoulopoulos, Chemosphere. 63, 212 (2006) http://dx.doi.org/10.1016/j.chemosphere.2005.08.020CrossrefGoogle Scholar

  • [17] J.Q. Jiang, S. Wang, Environ. Eng. Sci. 20, 627 (2003) http://dx.doi.org/10.1089/109287503770736140CrossrefGoogle Scholar

  • [18] A. Jain, V.K. Sharma, M.S. Mbuya, J. Hazard. Mater. 169, 339 (2009) http://dx.doi.org/10.1016/j.jhazmat.2009.03.101CrossrefGoogle Scholar

  • [19] V.K. Sharma, M. Sohn, Environ. Int. 35, 743 (2009) http://dx.doi.org/10.1016/j.envint.2009.01.005CrossrefGoogle Scholar

  • [20] R.A. Yngard, V.K. Sharma, J. Filip, R. Zboril, Environ. Sci. Technol. 42, 3005 (2008) http://dx.doi.org/10.1021/es0720816CrossrefGoogle Scholar

  • [21] K. Osathaphan, P. Tiyanont, R.A. Yngard, V.K. Sharma, Water Air Soil Pollut. 219, 5274 (2011) http://dx.doi.org/10.1007/s11270-010-0725-1CrossrefGoogle Scholar

  • [22] S. Licht, Energies 3, 960 (2010) http://dx.doi.org/10.3390/en3050960CrossrefGoogle Scholar

  • [23] J. Jiang, C. Stanford, M. Alsheyab, Sep. Purif. Technol. 68, 227 (2009) http://dx.doi.org/10.1016/j.seppur.2009.05.007CrossrefGoogle Scholar

  • [24] Z. Macova, K. Bouzek, J. Hives, V.K. Sharma, R.J. Terryn, J.C. Baum, Electrochim. Acta. 54, 2673 (2009) http://dx.doi.org/10.1016/j.electacta.2008.11.034CrossrefGoogle Scholar

  • [25] Y.D. Perfiliev, E.M. Benko, D.A. Pankratov, V.K. Sharma, S.D. Dedushenko, Inorg. Chim. Acta. 360, 2789 (2007) http://dx.doi.org/10.1016/j.ica.2006.11.019CrossrefGoogle Scholar

  • [26] Z. Mácová, K. Bouzek, V.K. Sharma, J. Appl. Electrochem. 40, 1019 (2010) http://dx.doi.org/10.1007/s10800-009-0051-8CrossrefGoogle Scholar

  • [27] Z. Luo, M. Strouse, J.Q. Jiang, V.K. Sharma, J. Environ. Sci. Health Part A. 46, 453 (2011) http://dx.doi.org/10.1080/10934529.2011.551723CrossrefGoogle Scholar

  • [28] D.A. Golovko, V.K. Sharma, V.I. Suprunovich, O.V. Pavlova, I.D. Golovko, K. Bouzek, K. Zboril, Anal. Lett. (2011) (In Press) Google Scholar

  • [29] J.M. Schreyer, G.W. Thompson, L.T. Ockerman, J. Am. Chem. Soc. 22, 1426 (1950) Google Scholar

  • [30] C. Zhang, F.-.F. Fan, A.J. Bard, J. Am. Chem. Soc. 131, 177 (2009) http://dx.doi.org/10.1021/ja8064254CrossrefGoogle Scholar

About the article

Published Online: 2011-07-24

Published in Print: 2011-10-01


Citation Information: Open Chemistry, Volume 9, Issue 5, Pages 808–812, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-011-0069-8.

Export Citation

© 2011 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Macarena A. Cataldo Hernández, Andrew May, Arman Bonakdapour, Madjid Mohseni, and David P. Wilkinson
Canadian Journal of Chemistry, 2017, Volume 95, Number 1, Page 105
[2]
Virender K. Sharma
Coordination Chemistry Reviews, 2013, Volume 257, Number 2, Page 495

Comments (0)

Please log in or register to comment.
Log in