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Open Chemistry

formerly Central European Journal of Chemistry

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Volume 9, Issue 6

Issues

Volume 13 (2015)

Ruthenium(II)-bis(4′-(4-ethynylphenyl)-2,2′:6′, 2″-terpyridine) — A versatile synthon in supramolecular chemistry. Synthesis and characterization

Ronald Siebert
  • Institute for Physical Chemistry, Jena Center for Soft Matter (JCSM), and Abbe Center of Photonics (ACP) Friedrich-Schiller-University Jena, 07743, Jena, Germany
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/ Florian Schlütter
  • Laboratory of Organic and Macromolecular Chemistry (IOMC) and Jena Center for Soft Matter (JCSM) Friedrich-Schiller-University Jena, 07743, Jena, Germany
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/ Andreas Winter
  • Laboratory of Organic and Macromolecular Chemistry (IOMC) and Jena Center for Soft Matter (JCSM) Friedrich-Schiller-University Jena, 07743, Jena, Germany
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/ Martin Presselt / Helmar Görls / Ulrich Schubert
  • Laboratory of Organic and Macromolecular Chemistry (IOMC) and Jena Center for Soft Matter (JCSM) Friedrich-Schiller-University Jena, 07743, Jena, Germany
  • Dutch Polymer Institute (DPI), P.O. Box 902, 5600 AX, Eindhoven, The Netherlands
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/ Benjamin Dietzek
  • Institute for Physical Chemistry, Jena Center for Soft Matter (JCSM), and Abbe Center of Photonics (ACP) Friedrich-Schiller-University Jena, 07743, Jena, Germany
  • Institute of Photonic Technology (IPHT) Jena, 07745, Jena, Germany
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/ Jürgen Popp
  • Institute for Physical Chemistry, Jena Center for Soft Matter (JCSM), and Abbe Center of Photonics (ACP) Friedrich-Schiller-University Jena, 07743, Jena, Germany
  • Institute of Photonic Technology (IPHT) Jena, 07745, Jena, Germany
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Published Online: 2011-09-27 | DOI: https://doi.org/10.2478/s11532-011-0087-6

Abstract

A homoleptic ethynyl-substituted ruthenium(II)-bisterpyridine complex representing a versatile synthon in supramolecular chemistry was synthesized and analyzed by NMR spectroscopy, mass spectrometry and X-ray diffractometry. Furthermore, its photophysical properties were detailed by UV/Vis absorption, emission and resonance Raman spectroscopy. In order to place the results obtained in the context of the vast family of ruthenium coordination compounds, two structurally related complexes were investigated accordingly. These reference compounds bear either no or an increased chromophore in the 4′-position. The spectroscopic investigations reveal a systematic bathochromic shift of the absorption and emission maximum upon increasing chromophore size. This bathochromic shift of the steady state spectra occurs hand in hand with increasing resonance Raman intensities upon excitation of the metal-to-ligand charge-transfer transition. The latter feature is accompanied by an increased excitation delocalization over the chromophore in the 4′-position of the terpyridine. Thus, the results presented allow for a detailed investigation of the electronic effects of the ethynyl substituent on the metal-to-ligand charge-transfer states in the synthon for click reactions leading to coordination polymers.

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About the article

Published Online: 2011-09-27

Published in Print: 2011-12-01


Citation Information: Open Chemistry, Volume 9, Issue 6, Pages 990–999, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-011-0087-6.

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© 2011 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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