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Open Chemistry

formerly Central European Journal of Chemistry


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Volume 10, Issue 1

Issues

Volume 13 (2015)

Synthesis of aluminosilicates under high pressure and using sulfur as directing agent

Sandra Loera / Enrique Lima / Heriberto Pfeiffer / Victor Lara
Published Online: 2011-11-24 | DOI: https://doi.org/10.2478/s11532-011-0123-6

Abstract

Two aluminosilicates were prepared under hydrothermal conditions. Silica, sodium aluminate, sodium sulfide and sulfur were used as raw materials. Starting with similar reacting mixtures, analcime (zeolite, Na(Si2Al)O6·H2O) and beidellite (clay, Na0.3Al2(Si, Al)4O10(OH)2·2H2O) were synthesized by varying pressures, 2 kbar and 1 kbar, respectively. Sulfur was present in both aluminosilicate surfaces, which confer to them particular adsorption properties. Additionally, water adsorption isotherms, under dynamical conditions, were obtained. Fractal dimension values and SEM micrographs reveal very different textural and morphological properties of the two prepared aluminosilicates

Keywords: Beidellite; Catalysts; Sulfur; Analcime; Small-angle X-ray scattering

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About the article

Published Online: 2011-11-24

Published in Print: 2012-02-01


Citation Information: Open Chemistry, Volume 10, Issue 1, Pages 105–112, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-011-0123-6.

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© 2011 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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