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Open Chemistry

formerly Central European Journal of Chemistry

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Volume 10, Issue 2

Issues

Volume 13 (2015)

The solubility of Ca(OH)2 in extremely concentrated NaOH solutions at 25°C

Attila Pallagi / Ágost Tasi / Attila Gácsi / Miklós Csáti / István Pálinkó / Gábor Peintler / Pál Sipos
Published Online: 2012-01-29 | DOI: https://doi.org/10.2478/s11532-011-0145-0

Abstract

The solubility of Ca(OH)2 in aqueous NaOH solutions up to 12.50 M at 25°C has been determined. The solubility data obtained for NaOH concentrations lower than 3 M was compared with those published in the literature. The solubility of Ca(OH)2 steadily decreases with the increasing NaOH concentration. The solubility data obtained at a constant ionic strength (I = 1 M Na(Cl,OH)) enabled the determination of the conditional solubility product of Ca(OH)2(s) (lgLCa(OH)2 = − 4.10 ± 0.02). Formation of the hydroxo complex CaOH+(aq) was invoked to describe the variation of [Ca2+]T with [OH−]T. Its conditional stability constant was found to be lgKCaOH+ = 0.97 ± 0.02. The experimental protocol employed was proven to be suitable for accurate solubility determinations in rapidly equilibrating systems comprising of highly concentrated, alkaline solutions and containing analytes in the ppm range.

Keywords: Solubility apparatus; Solubility; ICP AES; Ca(OH)2; Concentrated electrolytes; Aqueous solutions

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About the article

Published Online: 2012-01-29

Published in Print: 2012-04-01


Citation Information: Open Chemistry, Volume 10, Issue 2, Pages 332–337, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-011-0145-0.

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© 2012 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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