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Open Chemistry

formerly Central European Journal of Chemistry

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IMPACT FACTOR 2016 (Open Chemistry): 1.027
IMPACT FACTOR 2016 (Central European Journal of Chemistry): 1.460

CiteScore 2016: 0.61

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2391-5420
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Volume 10, Issue 4

Issues

Diironcarbonyl-coumarin complex: preparation, intramolecular electron transfer, and electro-generation of hydrogen

Charles Mebi / Joshua Trujillo / Anwar Bhuiyan
Published Online: 2012-05-29 | DOI: https://doi.org/10.2478/s11532-012-0048-8

Abstract

A new organometallic complex coupling photoactive coumarin to a diironhexacarbonyl unit has been successfully prepared and its composition and electronic structure confirmed by elemental and spectroscopic analyses. Emission spectral analysis of the complex reveals photoinduced intramolecular electron transfer from coumarin to the iron-carbonyl moiety. The compound is electrochemically reduced at −1.24 V vs. Fc/Fc+. This reduction is irreversible, attesting to the instability of the complex. Electrochemical evolution of hydrogen in the presence of the complex has been studied and results are discussed.

Keywords: Catalysis; Coumarin; Electron transfer; Hydrogenase model; Organometallic

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About the article

Published Online: 2012-05-29

Published in Print: 2012-08-01


Citation Information: Open Chemistry, Volume 10, Issue 4, Pages 1218–1222, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-012-0048-8.

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© 2012 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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