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Open Chemistry

formerly Central European Journal of Chemistry


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Volume 10, Issue 5

Issues

Volume 13 (2015)

Photometric determination of aqueous cobalt (II), nickel (II), copper (II) and iron (III) with 1-nitroso-2-naphthol-3,6-disulfonic acid disodium salt in gelatin films

Elena Reshetnyak
  • Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine
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/ Nataliia Ivchenko
  • Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine
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/ Nataliya Nikitina
  • Department of Chemical Metrology, Chemical Faculty, Kharkiv V.N. Karazin National University, Kharkiv, 61022, Ukraine
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Published Online: 2012-07-21 | DOI: https://doi.org/10.2478/s11532-012-0081-7

Abstract

Photometric determination of aqueous Co(II), Cu(II), Ni(II) and Fe(III) was performed using indicator films prepared by immobilization of 1-nitroso-2-naphthol-3,6-disulfonic acid disodium salt (NRS) into hardened photographic film. Immobilization was based on electrostatic interaction of reagent and metal complexes with the gelatin. The isoelectric point pH of hardened gelatin (4.46±0.04) was evaluated by viscometry. Co(II), Fe(III), Ni(II) form 1:3 complexes with NRS in gelatin at pH 2 and Cu(II) forms 1:2 complexes. Their log β′ values were: Co-6.7, Fe-8.6, Cu-8.0, and Ni-6.4. The absorption maxima were: 370nm for NRS, and 430nm, 470nm, 495nm and 720nm for complexes of Co(II), Ni(II), Cu(II) and Fe(III). An algorithm for their simultaneous determination using the indicator films was developed. The detection limits were: clim(Co2+) = 0.45×10−5 M, clim(Fe3+) = 0.50×10−5 M, clim(Cu2+) = 0.67×10−5 M, clim(Ni2+) = 0.75×10−5 M,; and their sum clim(ΣMn+) = 0.82×10−5 M.

Keywords: Nitroso-R-salt; Gelatin film; Immobilization; Metal ions; Complex

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About the article

Published Online: 2012-07-21

Published in Print: 2012-10-01


Citation Information: Open Chemistry, Volume 10, Issue 5, Pages 1617–1623, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-012-0081-7.

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© 2012 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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