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Open Chemistry

formerly Central European Journal of Chemistry

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Volume 11, Issue 3

Issues

Volume 16 (2018)

Volume 15 (2017)

Volume 14 (2016)

Volume 13 (2015)

Volume 12 (2014)

Volume 11 (2013)

Volume 10 (2012)

Volume 9 (2011)

Volume 8 (2010)

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Volume 1 (2003)

Electrochemical study of dsDNA on carbon nanotubes paste electrodes applying cyclic and differential pulse voltammetry

Constantina Serpi / Anastasios Voulgaropoulos / Stella Girousi
Published Online: 2012-12-28 | DOI: https://doi.org/10.2478/s11532-012-0180-5

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Abstract

Abstract Carbon nanotubes paste electrodes (CNTPEs) in combination with adsorptive transfer stripping voltammetry are shown to be very suitable for the determination of calf thymus double-stranded DNA (dsDNA). The performance of three types of multi-walled carbon nanotubes paste electrodes (MWCNTPEs) is investigated. The effects of surface pre-treatment and accumulation conditions on the adsorption and electrooxidation of the dsDNA at MWCNTPEs are also described. The results indicate that the electroactivity inherent to carbon nanotubes/paste electrodes allows a large enhancement of the guanine oxidation signal compared to that obtained at the conventional carbon paste electrodes (CPEs). Moreover, the extent of the enhancement dependents on the type of MWCNTs incorporated into the paste. Based on the signal of guanine, under optimal conditions, very low levels of dsDNA can be detected following short accumulation times for all three types of MWCNTPEs (MWCNTPE1, MWCNTPE2, MWCNTPE3), with detection limits of 2.64 mg L−1, 2.02 mg L−1 and 1.46 mg L−1, respectively. Additionally, the dsDNA isolated from rat liver tissues is determined by use of the previously mentioned MWCNTPEs. Graphical abstract

Keywords: Carbon nanotubes paste electrodes; Carbon paste electrode; dsDNA; Adsorptive transfer stripping voltammetry

  • [1] K.B. Wu, J.J. Fei, S.S. Hu, Anal. Biochem. 318, 100 (2003) http://dx.doi.org/10.1016/S0003-2697(03)00174-XCrossrefGoogle Scholar

  • [2] G. Wang, J.J. Xu, H.Y. Chen, Electrochem. Commun. 4, 506 (2002) http://dx.doi.org/10.1016/S1388-2481(02)00360-0CrossrefGoogle Scholar

  • [3] U. Yogeswaran, S. Thiagarajan, S.M. Chen, Anal. Biochem. 365, 122 (2007) http://dx.doi.org/10.1016/j.ab.2007.02.034CrossrefGoogle Scholar

  • [4] Y.C. Tsai, C.C. Chiu, Sens. Actuator B: Chem. 125, 10 (2007) http://dx.doi.org/10.1016/j.snb.2007.01.032CrossrefGoogle Scholar

  • [5] J.X. Zeng, X.H. Gao, W.Z. Wei, X.R. Zhai, J. Yin, L. Wu, X.Y. Liu, K. Liu, S.G. Gong, Sens. Actuator B: Chem. 120, 595 (2007) http://dx.doi.org/10.1016/j.snb.2006.03.016CrossrefGoogle Scholar

  • [6] J.M. Xu, Y.P. Wang, Y.Z. Xian, L.T. Jin, K. Tanaka, Talanta 60, 1123 (2003) http://dx.doi.org/10.1016/S0039-9140(03)00214-5CrossrefGoogle Scholar

  • [7] Y.D. Zhao,W.D. Zhang, H. Chen, Q.M. Luo, Talanta 58, 529 (2002) http://dx.doi.org/10.1016/S0039-9140(02)00318-1CrossrefGoogle Scholar

  • [8] S.G. Wang, Q. Zhang, R. Wang, S.F. Yoon, J. Ahn, D.J. Yang, J.Z. Tian, J.Q. Li, Q. Zhou, Electrochem. Commun. 5, 800 (2003) http://dx.doi.org/10.1016/j.elecom.2003.07.007CrossrefGoogle Scholar

  • [9] P.F. Liu, J.H. Hu, Sens. Actuator B: Chem. 8, 194 (2002) http://dx.doi.org/10.1016/S0925-4005(02)00024-2CrossrefGoogle Scholar

  • [10] H. Zhu G.C. Zhao, Microchim. Acta 165, 329 (2009) http://dx.doi.org/10.1007/s00604-009-0138-2CrossrefGoogle Scholar

  • [11] J. Wang, Y. Lin, Trends in Anal. Chem. 27, 619 (2008) http://dx.doi.org/10.1016/j.trac.2008.05.009CrossrefGoogle Scholar

  • [12] A. Ferancová, J. Labuda, (WILEY-VCH Verlag, 2008) Google Scholar

  • [13] M.L. Pedano, G.A. Rivas, Electrochem. Commun. 6, 10 (2004) http://dx.doi.org/10.1016/j.elecom.2003.10.008CrossrefGoogle Scholar

  • [14] H. Qi, X. Li, P. Chen, C. Zhang, Talanta 72, 1030 (2007) http://dx.doi.org/10.1016/j.talanta.2006.12.032CrossrefGoogle Scholar

  • [15] I. Balan, I.G. David, V. David, A.I. Stoica, C. Mihailciuc, I. Stamatin, A.A. Ciucu, J. Electr. Chemi. 654, 8 (2011) http://dx.doi.org/10.1016/j.jelechem.2011.02.002CrossrefGoogle Scholar

  • [16] S.Y. Ly, H.-S. Yoo, S.H. Choa, J. Microb. Meth. 87, 44 (2011) http://dx.doi.org/10.1016/j.mimet.2011.07.002CrossrefGoogle Scholar

  • [17] S.Y. Ly, N.S. Chob, J. Clinic Virol. 44, 43 (2009) http://dx.doi.org/10.1016/j.jcv.2008.09.005CrossrefGoogle Scholar

  • [18] P. Palaska, E. Aritzoglou, S. Girousi, Talanta 72, 1199 (2007) http://dx.doi.org/10.1016/j.talanta.2007.01.013CrossrefGoogle Scholar

  • [19] V. Brabec, J. Koudelka, Bioelectrochem. Bioenerg. 7, 793 (1980) http://dx.doi.org/10.1016/0302-4598(80)80043-2CrossrefGoogle Scholar

  • [20] G.A. Rivas, M.D. Rubianes, M.C. Rodríguez, N.F. Ferreyra, G.L. Luque, M.L. Pedano, S.A. Miscoria, C. Parrado, Talanta 74, 291 (2007) http://dx.doi.org/10.1016/j.talanta.2007.10.013CrossrefGoogle Scholar

  • [21] H. Qi, X. Li, P. Chen, C. Zhang, Talanta 72, 1030 (2007) http://dx.doi.org/10.1016/j.talanta.2006.12.032CrossrefGoogle Scholar

  • [22] J. Wang, G. Rivas, X. Cai, M. Chicharro, N. Dontha, D. Luo, E. Palecek, P. Nielsen, Electroanalysis 9, 120 (1997) http://dx.doi.org/10.1002/elan.1140090206CrossrefGoogle Scholar

  • [23] B.J. Taft, A.D. Lazareck, G.D. Withey, A. Yin, J.M. Xu, S.O. Kelley, J. Am. Chem. Soc. 126, 12750 (2004) http://dx.doi.org/10.1021/ja045543dCrossrefGoogle Scholar

  • [24] C. Kokkinos, I. Raptis, A. Economou, T. Speliotis, Electroanalysis 22, 2359 (2010) http://dx.doi.org/10.1002/elan.201000252CrossrefGoogle Scholar

About the article

Published Online: 2012-12-28

Published in Print: 2013-03-01

Citation Information: Open Chemistry, Volume 11, Issue 3, Pages 413–423, ISSN (Online) 2391-5420, DOI: https://doi.org/10.2478/s11532-012-0180-5.

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© 2012 Versita Warsaw. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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