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Open Chemistry

formerly Central European Journal of Chemistry

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IMPACT FACTOR 2016 (Open Chemistry): 1.027
IMPACT FACTOR 2016 (Central European Journal of Chemistry): 1.460

CiteScore 2016: 0.61

SCImago Journal Rank (SJR) 2016: 0.288
Source Normalized Impact per Paper (SNIP) 2016: 0.735

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ISSN
2391-5420
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Volume 13, Issue 1

Issues

Treatment of wastewaters containing acid, reactive and direct dyes using aminosilane functionalized silica

Monika Wawrzkiewicz
  • Corresponding author
  • Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie – Sklodowska University, 20-031 Lublin, Poland
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Zbigniew Hubicki
  • Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie – Sklodowska University, 20-031 Lublin, Poland
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  • De Gruyter OnlineGoogle Scholar
/ Magdalena Nowacka
  • Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Poznan University of Technology, 60-965 Poznan, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Łukasz Klapiszewski
  • Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Poznan University of Technology, 60-965 Poznan, Poland
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  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-10-09 | DOI: https://doi.org/10.1515/chem-2015-0013

Abstract

Aminosilane modified silica was prepared and investigated for the adsorption of textile dyes such as C.I. Acid Orange 7 (AO7), C.I. Reactive Black 5 (RB5) and C.I. Direct Blue 71 (DB71) from aqueous media and wastewaters. The values of the sorption capacities obtained from the Langmuir isotherm model were: 5.3 mg g-1, 58.7 mg g-1 and 72.2 mg g-1 for AO7, DB71 and RB5, respectively. The affinity series of the dyes for the modified silica can be presented as follows: C.I. Reactive Black 5 > C.I. Direct Blue 71> C.I. Acid Orange 7. The influence of anionic surfactant (SDS) and sodium chloride on dye sorption was investigated in a system containing 100 mg L-1 dye and 0.1-1 g L-1 SDS or 1-25 g L-1 NaCl. The sorption capacities decrease with increasing concentration of SDS in the solution. Retention of AO7 and RB5 was reduced in the presence of NaCl. A satisfactory agreement of the experimental data with the pseudo second-order kinetic model was found. Effectiveness of the aminosilane modified silica in raw textile wastewater purification was confirmed.

Graphical Abstract

Keywords : dye sorption; modified silica; wastewater purification; kinetic studies; dyes removal

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About the article

Received: 2013-11-06

Accepted: 2014-03-19

Published Online: 2014-10-09

Published in Print: 2015-01-01


Citation Information: Open Chemistry, Volume 13, Issue 1, ISSN (Online) 2391-5420, DOI: https://doi.org/10.1515/chem-2015-0013.

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