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Open Chemistry

formerly Central European Journal of Chemistry

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IMPACT FACTOR 2016 (Open Chemistry): 1.027
IMPACT FACTOR 2016 (Central European Journal of Chemistry): 1.460

CiteScore 2016: 0.61

SCImago Journal Rank (SJR) 2016: 0.288
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2391-5420
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Volume 13, Issue 1 (Dec 2014)

Issues

Enhancing the surface properties of linen by non-thermal atmospheric air-plasma treatment

Orsolya Erzsébet Szabó
  • Corresponding author
  • Department of Physical Chemistry and Materials Science, Budapest University of Technology and Economics, H-1521 Budapest, P.O. Box 91, Hungary
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Emília Csiszár
  • Department of Physical Chemistry and Materials Science, Budapest University of Technology and Economics, H-1521 Budapest, P.O. Box 91, Hungary
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ András Tóth
  • Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, Pusztaszeri út 59-67. H-1025 Budapest, Hungary
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-12-22 | DOI: https://doi.org/10.1515/chem-2015-0068

Abstract

In this research, a diffuse coplanar surface barrier discharge (DCSBD) type plasma reactor was used for the surface modification of raw linen fabric. Changes in physical properties and chemical composition of the fiber surface as well as color of the fabric were measured as a function of time of the atmospheric air plasma treatment. Furthermore, ageing of the effects created on the fiber surface by plasma treatment was also characterized in a period of 0-14 days elapsed after the plasma treatment. Significant differences were found between the properties of the raw and plasma treated linen fabrics, including increase of wettability, wickability, surface energy and O/C ratio, and decrease of water contact angle and deterioration of the waxy outer layer of the fibers. Most of the parameters depended on the time of plasma treatment (0–180 s). O/C ratio increased steadily with the increase of duration of the plasma treatment, which was explained by destruction of the waxy surface layer, creation of polar groups and exposure of cellulosic components. Most of the properties tested were found to be stable during two weeks of storage after the plasma treatment, indicating that the surface ‘topography’ created by plasma remained almost unaltered and the recovery of the etched waxy coverage of the fiber did not occur.

Graphical Abstract

Keywords : Hydrophilicity; Wetting; Wicking; Surface chemical composition; Ageing of plasma effects

References

  • [1] Verschuren J., Kiekens P., Leys C., Textile-specific properties that influence plasma treatment, effect creation and effect characterization, Text. Res. J., 2007, 77(10), 727-733. Web of ScienceGoogle Scholar

  • [2] Sadova S.F., Pankratova E.V., Low-temperature plasma surface modification of textiles made from natural fibers and advanced technologies, High Energ. Chem+., 2008, 43(3), 234-240. CrossrefGoogle Scholar

  • [3] Morent R., De Geyter N., Verschuren J., De Clerck K., Kiekens P., Leys C., Non-thermal plasma treatment of textiles, Surf. Coat. Tech., 2008, 202, 3427-3449. Google Scholar

  • [4] Bhat N.V., Netravali A.N., Gore A.V., Sathianarayanan M.P., Arolkar G.A., Deshmukh R.R., Surface modification of cotton fabrics using plasma technology, Text. Res. J., 2011, 81, 1014-1026. Web of ScienceGoogle Scholar

  • [5] Nithya E., Radhai R., Rajendran R., Jayakumar S., Vaideki K., Enhancement of the antimicrobial property of cotton fabric using plasma and enzyme pre-treatments, Carbohyd. Polym., 2012, 88, 986-991. Web of ScienceGoogle Scholar

  • [6] Karahan H.A., Özdogan E., Improvements of surface functionality of cotton fibers by atmospheric plasma treatment, 2008, Fiber. Polym., 9, 21-26. Google Scholar

  • [7] Tian L., Nie H., Chatterton N.P., Branford-White C.J., Qiu Y., Zhu L., Helium/oxygen atmospheric pressure plasma jet treatment for hydrophilicity improvement of grey cotton knitted fabric, Appl. Surf. Sci., 2011, 257, 7113-7118. Web of ScienceGoogle Scholar

  • [8] Carrino L., Polini W., Sorrentino L., Ageing time of wettability on polypropylene surfaces processed by cold plasma, J. Mater. Process. Tech., 2004, 153–154, 519-525. Google Scholar

  • [9] Sun S., Sun J., Yao L., Qiu Y., Wettability and sizing property improvement of raw cotton yarns treated with He/O2 atmospheric pressure plasma jet, Appl. Surf. Sci., 2011, 257, 2377-2382. Web of ScienceGoogle Scholar

  • [10] Focet B., Marzetti A., Sharma H.S.S., Changes in the structure and properties of flax fibre during processing, In: Sharma H.S.S., Van Sumere C.F. (Eds.), The Biology and Processing of Flax, M Publications, Belfast, 1992 Google Scholar

  • [11] Ryser U., Holloway P.J., Ultrastructure and chemistry of soluble and polymeric lipids in cell walls from seed coats and fibres of gossypium species, Planta, 1985, 163, 151-163. Google Scholar

  • [12] Ibrahim N.A., Hashem M.M., Eid M.A., Refai R., El-Hossamy M., Eid B.M., Eco-friendly plasma treatment of linen-containing fabrics, J. Text. I., 2010, 101(12), 1035-1049. Web of ScienceGoogle Scholar

  • [13] Ibrahim N.A., El-Hossamy M., Hashem M.M., Refai R., Eid B.M., Novel pre-treatment processes to promote linen-containing fabrics properties, Carbohyd. Polym., 2008, 74(4), 880-891. Web of ScienceGoogle Scholar

  • [14] Csiszár E., Surface properties and residual chromophore content of differently pretreated linen fabrics, Text. Res. J., 2012, 82(19), 2030-2040. Web of ScienceGoogle Scholar

  • [15] Kissa E., Wetting and wicking, Text. Res. J., 1966, 66, 660-668. Google Scholar

  • [16] Owens D.K., Wendt R.C., Estimation of the surface free energy of polymers, J. Appl. Polym. Sci., 1969, 13, 1741-1747. Google Scholar

  • [17] Song K.H., Obendorf S.K., Chemical and biological retting of kenaf fibers. Text. Res. J., 2006, 76(10), 751-756. Google Scholar

  • [18] Laine J., Stenius P., Carlsson G., Ström G., Surface characterization of unbleached kraft pulps by means of ESCA, Cellulose, 1994, 1, 145-160. Google Scholar

  • [19] Buchert J., Carlsson G., Viikari L., Ström G., Surface characterization of unbleached kraft pulps by enzymatic peeling by ESCA, Holzforschung, 1996, 50, 69-74. Google Scholar

  • [20] Chung C., Lee M., Choe E.K., Characterization of cotton fabric scouring by FT-IR ATR spectroscopy, Carbohyd. Polym., 2004, 58, 417-420. Google Scholar

  • [21] Evans J. D., Akin D.E., Foulk J.A., Flax-retting by polygaracturonase-containing enzyme mixtures and effects on fiber properties, J. Biotechnol., 2002, 97, 223-231. Google Scholar

  • [22] Karaca B., Csiszár E., Bozdogan F., Effects of atmospheric plasma pre-treatments on pectinase efficiency in bioscouring of linen fabrics, Plasma Chem. Plasma P., 2011, 31(4), 623-633. CrossrefGoogle Scholar

About the article

Received: 2014-01-31

Accepted: 2014-04-15

Published Online: 2014-12-22


Citation Information: Open Chemistry, ISSN (Online) 2391-5420, DOI: https://doi.org/10.1515/chem-2015-0068.

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© 2015 Szabó, O.E et al.. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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