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Open Chemistry

formerly Central European Journal of Chemistry

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Volume 13, Issue 1


Volume 13 (2015)

Enhancing the surface properties of linen by non-thermal atmospheric air-plasma treatment

Orsolya Erzsébet Szabó
  • Corresponding author
  • Department of Physical Chemistry and Materials Science, Budapest University of Technology and Economics, H-1521 Budapest, P.O. Box 91, Hungary
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Emília Csiszár
  • Department of Physical Chemistry and Materials Science, Budapest University of Technology and Economics, H-1521 Budapest, P.O. Box 91, Hungary
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ András Tóth
  • Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, Pusztaszeri út 59-67. H-1025 Budapest, Hungary
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-12-22 | DOI: https://doi.org/10.1515/chem-2015-0068


In this research, a diffuse coplanar surface barrier discharge (DCSBD) type plasma reactor was used for the surface modification of raw linen fabric. Changes in physical properties and chemical composition of the fiber surface as well as color of the fabric were measured as a function of time of the atmospheric air plasma treatment. Furthermore, ageing of the effects created on the fiber surface by plasma treatment was also characterized in a period of 0-14 days elapsed after the plasma treatment. Significant differences were found between the properties of the raw and plasma treated linen fabrics, including increase of wettability, wickability, surface energy and O/C ratio, and decrease of water contact angle and deterioration of the waxy outer layer of the fibers. Most of the parameters depended on the time of plasma treatment (0–180 s). O/C ratio increased steadily with the increase of duration of the plasma treatment, which was explained by destruction of the waxy surface layer, creation of polar groups and exposure of cellulosic components. Most of the properties tested were found to be stable during two weeks of storage after the plasma treatment, indicating that the surface ‘topography’ created by plasma remained almost unaltered and the recovery of the etched waxy coverage of the fiber did not occur.

Graphical Abstract

Keywords : Hydrophilicity; Wetting; Wicking; Surface chemical composition; Ageing of plasma effects


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About the article

Received: 2014-01-31

Accepted: 2014-04-15

Published Online: 2014-12-22

Citation Information: Open Chemistry, Volume 13, Issue 1, ISSN (Online) 2391-5420, DOI: https://doi.org/10.1515/chem-2015-0068.

Export Citation

© 2015 Szabó, O.E et al.. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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