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Open Chemistry

formerly Central European Journal of Chemistry

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IMPACT FACTOR 2016 (Open Chemistry): 1.027
IMPACT FACTOR 2016 (Central European Journal of Chemistry): 1.460

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2391-5420
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Volume 13, Issue 1 (Jun 2015)

Issues

Liquid chromatographic determination of glyphosate and aminomethylphosphonic acid residues in rapeseed with MS/MS detection or derivatization/fluorescence detection

Piotr Kaczyński
  • Corresponding author
  • Institute of Plant Protection – National Research Institute, Chełmońskiego 22, 15-195 Bialystok, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Bożena Łozowicka
  • Institute of Plant Protection – National Research Institute, Chełmońskiego 22, 15-195 Bialystok, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2015-06-22 | DOI: https://doi.org/10.1515/chem-2015-0107

Abstract

Glyphosate and AMPA determinations in rapeseed extracts by (a) liquid chromatography with triple quadrupole MS detection (LC-MS/MS), or (b) liquid chromatography with post-column OPA derivatization and fluorescence detection (LC-FLD) were developed. Mean recoveries for glyphosate and AMPA were (a) 88.8–95.0% and 82.1–86.1%, and (b) 70.8–74.1% and 62.4–72.6%. RSD were below (a) 11% and (b) 22%. Correlation coefficients were above 0.997 for both methods. LOD were 0.01 mg kg-1 for (a) and 0.05 mg kg-1 for (b). Both methods are simple and efficient for routine analysis of glyphosate and AMPA in a fatty matrix.

Graphical Abstract

Keywords : glyphosate; AMPA; rapeseed; liquid chromatography; mass spectrometry

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About the article

Received: 2014-12-08

Accepted: 2015-04-01

Published Online: 2015-06-22


Citation Information: Open Chemistry, ISSN (Online) 2391-5420, DOI: https://doi.org/10.1515/chem-2015-0107.

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© 2015 Piotr Kaczyński, Bożena Łozowicka. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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