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Volume 64, Issue 6

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A naked-eye, selective and sensitive chemosensor for fluoride ion

Puhui Xie / Fengqi Guo / Weifeng Wang / Xiyang Liu
Published Online: 2010-09-23 | DOI: https://doi.org/10.2478/s11696-010-0060-4

Abstract

Effect of the addition of six different anions on the absorption and fluorescence spectra of acridine yellow G (AYG) was examined. Only the F− anion could induce a visible color change observable with naked eye and a strong fluorescence quenching with K SV of 8.3 × 104 mol−1 L in CH3CN solutions. Calculated results of the interaction between the F− anion and acridine yellow G using the B3LYP/6-31G(d) program showed that the intermolecular charge transfer through the formation of an H-bond between AYG and F− is an essential sensor mechanism.

Keywords: fluoride ion; chemosensor; acridine yellow G; hydrogen bonding

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About the article

Published Online: 2010-09-23

Published in Print: 2010-12-01


Citation Information: Chemical Papers, Volume 64, Issue 6, Pages 723–728, ISSN (Online) 1336-9075, DOI: https://doi.org/10.2478/s11696-010-0060-4.

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© 2010 Institute of Chemistry, Slovak Academy of Sciences.

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