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Catalysis for Sustainable Energy

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Role of MoVTeNb oxide catalyst constituent phases in propane oxidation to acrylic acid.

Evgeniya V. Ishchenko / Galina Ya. Popova / Tatyana Yu. Kardash
  • Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
  • Novosibirsk State University, Novosibirsk, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Arcady V. Ishchenko / Ludmila M. Plyasova / Tamara V. Andrushkevich
Published Online: 2013-03-15 | DOI: https://doi.org/10.2478/cse-2013-0003

Abstract

The catalytic activity of MoVTeNbO catalyst and its constituent phases (M1, M2 and Mo5O14-like) in the oxidation of propane, as well as propylene and acrolein, which are intermediates of acrylic acid formation from propane, was studied. In all the reactions, the М1 phase shows higher activity and selectivity, compared to M2 and Mo5O14-like phases; its presence being sufficient for efficient proceeding the propane oxidation to acrylic acid.

Keywords: Propane oxidation; Acrylic acid; Active site; M1; M2; Mo5O14-like phases

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About the article


Received: 2012-12-21

Accepted: 2013-01-23

Published Online: 2013-03-15


Citation Information: Catalysis for Sustainable Energy, Volume 1, Pages 75–81, ISSN (Online) 2084-6819, DOI: https://doi.org/10.2478/cse-2013-0003.

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