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Catalysis for Sustainable Energy

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Colloidal catalysts on the base of iron(3+) oxides for oxidative treatment of biomass

O.T. Kasaikina / V.I. Lesin / L.M. Pisarenko
Published Online: 2014-02-24 | DOI: https://doi.org/10.2478/cse-2014-0003


The analysis of the chemical nature of wood waste processing by fungus and bacteria was the starting point for innovative production of a new, relatively simple, colloidal catalytic system based on iron (III) oxides, combined with environmentally friendly oxidants - hydrogen peroxide and/or atmospheric oxygen. Colloidal iron(III) oxides, obtained by hydrolysis of Fe(III) salts in water in the presence of surfactants, catalyze the oxidative destruction of lignocellulosic biomass under atmospheric pressure, at a mild temperature range of 60-70oC, under the influence of H2O2 and O2. The oxidative destruction of biomass (wood sawdust, peat, olive press cake, oat straw) results in formation of light organic acids, esters and other low molecular oxidation products derived from lignin, hemicelluloses, cellulose, lipoproteins and sugars; the solid product constitutes mainly of cellulose and its derivatives. The yield of solid residue depends on biomass nature, reagents concentration ratio (biomass, catalyst, hydrogen peroxide), and oxidation process duration. Water solution of organic acids and esters can be used in agriculture for fodder processing.

Keywords: lignocellulosic biomass treatment, iron(III) oxides, hydrogen peroxide, catalytic oxidation, catalyst transformation, cellulose, organic acids and esters;


  • [1] http://www.nnfcc.co.uk/tools/marketing-study-for-biomass-treatment-technology-nnfcc-10-003#sthash.r86erW2E.dpuf Google Scholar

  • [2] Kamm, B. and Kamm, M. Biorefineries–multi product processes. Adv. Biochem Engin/Biotechnol , 2007; 105, 175–204. Google Scholar

  • [3] Kumar, P., Barrett, D.M., Delwiche, M.J., and Stroeve, P. Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production. Ind. Eng. Chem. Res., 2009; 48 (8), 3713–3729. Web of ScienceCrossrefGoogle Scholar

  • [4] D.Mohan, C.U.Pittman, Jr., and P.H.Steele, Pyrolysis of Wood/Biomass for Bio-Oil: A Critical Review, Energy & Fuels, 2006; 20, 848-889. CrossrefGoogle Scholar

  • [5] McMillan, J.D. Pretreatment of lignocellulosic biomass, in Enzymatic Conversion of Biomass for Fuels Production, ed by Himmel, M.E., Baker, J.O., and Overend, R.P. American Chemical Society, Washington, DC, USA, 1994; 292–324. Google Scholar

  • [6] Zheng, Y., Pan, Z., and Zhang, R. Overview of biomass pretreatment for cellulosic ethanol production. Int. J. Agric. Biol. Eng. 2009; 2, 51–68. Google Scholar

  • [7] Galbe, M., and Zacchi, G. A review of the production of ethanol from softwood. Appl. Microbiol. Biot. 2002; 59, 618–628. CrossrefGoogle Scholar

  • [8] Tomas-Pejo, E., Oliva, J.M., & Ballesteros, M. Realistic approach for full-scale bioethanol production from lignocellulose: a review. Journal of Scientific & Industrial Research. 2008; 67, 874–884. Google Scholar

  • [9] Mosier, N., Wyman, C., Dale, B., Elander, R., Lee, Y.Y., Holtzapple, M. and Ladisch, M. Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresource Technol. 2005; 96, 673–686. CrossrefGoogle Scholar

  • [10] Harmsen, P.F.H., Huijgen, W.J.J., Bermudez Lopez, L.M., & Bakker, R.R.C. Literature Review of Physical and Chemical Pre-treatment Processes for Lignocellulosic Biomass. Energy Research Centre of the Netherlands. Report accessed on January 2010. Web Address: http://www.ecn.nl/docs/library/report/2010/e10013.pdf Google Scholar

  • [11] Michel, H. About the Nonsense of Biofuels, Angew. Chem. Int. Ed. 2012; 51(11), 2516-517. CrossrefGoogle Scholar

  • [12] Kirk T.K. in Microbial Degradation of Organic Compounds, ed. Gibson D.T., Marcel Dekker, Inc., New York, 1984; 13, 399-438. Google Scholar

  • [13] Boeran W., Ralph J., Baucher M., Lignin biosynthesis. Annu. Rev.Plant Biol., 2003; 54, 519-549.CrossrefGoogle Scholar

About the article

Received: 2013-11-01

Accepted: 2013-12-24

Published Online: 2014-02-24

Citation Information: Catalysis for Sustainable Energy, Volume 2, Issue 1, Pages 21–27, ISSN (Online) 2084-6819, DOI: https://doi.org/10.2478/cse-2014-0003.

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©2014 Kasaikina O.T. et al.. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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