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Catalysis for Sustainable Energy

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Hydrogen generation by both acidic and catalytic hydrolysis of sodium borohydride

Olga V. Netskina
  • Corresponding author
  • Laboratory of Hydrides Investigation, Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, Novosibirsk, 630090, Russia
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Tihon N. Filippov
  • Photocatalysis group, Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, Novosibirsk, 630090, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Oksana V. Komova
  • Laboratory of Hydrides Investigation, Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, Novosibirsk, 630090, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Valentina I. Simagina
  • Laboratory of Hydrides Investigation, Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, Novosibirsk, 630090, Russia
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2018-12-31 | DOI: https://doi.org/10.1515/cse-2018-0006

Abstract

Sodium borohydride tablets have been employed as hydrogen-storage materials. Hydrogen release was performed by acidic hydrolysis where solutions of sulfuric and hydrochloric acids were added to the tablets, and by catalytic hydrolysis where water was added tablets of solid-state NaBH4/Co composite. In acidic solutions hydrogen evolution occurred instantaneously, and at high concentrations of acids the releasing hydrogen contained an admixture of diborane. Hydrogen evolution from the solidstate NaBH4/Co composite proceeded at a uniform rate of 13.8±0.1 cm3·min-1, water vapor being the only impurity in the evolving gas.

Keywords: Hydrogen; sodium borohydride; acid hydrolysis; diborane; catalyst hydrolysis

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About the article

Received: 2018-10-09

Accepted: 2018-10-16

Published Online: 2018-12-31

Published in Print: 2018-12-01


Citation Information: Catalysis for Sustainable Energy, Volume 5, Issue 1, Pages 41–48, ISSN (Online) 2084-6819, DOI: https://doi.org/10.1515/cse-2018-0006.

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© by Olga V. Netskina, et al., published by De Gruyter. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License. BY-NC-ND 4.0

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