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Catalysis for Sustainable Energy

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Catalytic myrtenol amination over gold, supported on alumina doped with ceria and zirconia

Yu.S. Demidova
  • Boreskov Institute of Catalysis, pr. Lavrentieva, 5, 630090, Novosibirsk, Russia
  • Novosibirsk State University, Pirogova 2, 630090, Novosibirsk, Russia
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/ I.L. Simakova
  • Corresponding author
  • Boreskov Institute of Catalysis, pr. Lavrentieva, 5, 630090, Novosibirsk, Russia
  • Novosibirsk State University, Pirogova 2, 630090, Novosibirsk, Russia
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/ E.V. Suslov / K.P. Volcho
  • Novosibirsk State University, Pirogova 2, 630090, Novosibirsk, Russia
  • Novosibirsk Institute of Organic Chemistry, pr. Lavrentieva, 9, 630090, Novosibirsk, Russia
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/ N.F. Salakhutdinov
  • Novosibirsk State University, Pirogova 2, 630090, Novosibirsk, Russia
  • Novosibirsk Institute of Organic Chemistry, pr. Lavrentieva, 9, 630090, Novosibirsk, Russia
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/ A. Simakov
  • Universidad Nacional Autonoma de Mexico, Centro de Nanociencias y Nanotecnologia, km. 107 carretera Tijuana a Ensenada, C.P. 22860, Ensenada, Baja California, Mexico
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/ D.Yu. Murzin
  • Johan Gadolin Process Chemistry Centre, Abo Akademi University, Biskopsgatan 8, FI-20500, Turku/Abo, Finland
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Published Online: 2018-12-31 | DOI: https://doi.org/10.1515/cse-2018-0007

Abstract

In the current work gold catalysts supported on both commercial oxides and oxides synthesized by the sol-gel method were used for the one-pot alcohol amination of myrtenol. In general, utilization of metal oxides synthesized by the sol-gel method as the gold catalyst support enhanced the knowledge regarding key parameters determining catalytic behavior. Synthesized alumina was characterized by stronger acid sites favoring primary amine accumulation on the catalyst surface, as compared to the commercial oxide. Utilization of mixed metal oxides synthesized by the sol-gel method resulted in the non-additive behavior of different oxides enhancing the catalytic activity. Introduction of ceria into alumina modified the support basicity resulting in more efficient alcohol activation.

Keywords: one-pot alcohol amination; gold; mixed oxides; ceriaalumina; ceria-alumina-zirconia; alumina; terpene alcohol

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About the article

Received: 2018-10-29

Accepted: 2018-11-08

Published Online: 2018-12-31

Published in Print: 2018-12-01


Citation Information: Catalysis for Sustainable Energy, Volume 5, Issue 1, Pages 49–58, ISSN (Online) 2084-6819, DOI: https://doi.org/10.1515/cse-2018-0007.

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© by Yu.S. Demidova, et al., published by De Gruyter. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License. BY-NC-ND 4.0

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