Editor-in-Chief: Agarwal, Seema / Greiner, Andreas
6 Issues per year
IMPACT FACTOR 2017: 1.111
CiteScore 2017: 1.02
SCImago Journal Rank (SJR) 2017: 0.335
Source Normalized Impact per Paper (SNIP) 2017: 0.430
Synthesis and structure-property relationships of novel poly(p-xylylene)s with aromatic substituents
Two step synthesis of educts for the synthesis of poly(p-xylylene)s was accomplished by Grignard-type coupling reaction of 4-bromotoluene and different aldehydes or p-tolylaldehyde and different aryl bromides followed by conversion of alcohols into corresponding chlorides. Derivatives of poly(p-xylylene) (PPX) were obtained by vapor phase pyrolysis/chemical vapor deposition (CVD) or Gilch-type polymerization of these chlorides. Functional groups along the PPX main chain were introduced by substituted phenyl rings in a-position. The resulting PPXs are soluble under ambient conditions and are amorphous in the solid state. The glass transition temperatures varied only slightly with substituents on the phenyl ring in a-position. Significant enhancement by substituents was found for the thermal stability under nitrogen and a considerable decrease of the surface energies by fluorinated substituents.