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e-Polymers

Editor-in-Chief: Agarwal, Seema


IMPACT FACTOR 2018: 1.491

CiteScore 2018: 1.31

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Source Normalized Impact per Paper (SNIP) 2018: 0.432

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1618-7229
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Volume 2, Issue 1

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Volume 1 (2001)

Synthesis and properties of novel poly(p-xylylene)s with aliphatic substituents

Michael Ishaque
  • Philipps-University Marburg, Department of Chemistry and Scientific Centre for Materials Science, Hans-Meerwein-Str., 35032 Marburg, Germany; Fax +49-6421-2825785
  • Other articles by this author:
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/ Seema Agarwal
  • Philipps-University Marburg, Department of Chemistry and Scientific Centre for Materials Science, Hans-Meerwein-Str., 35032 Marburg, Germany; Fax +49-6421-2825785
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  • De Gruyter OnlineGoogle Scholar
/ Andreas Greiner
  • Corresponding author
  • Philipps-University Marburg, Department of Chemistry and Scientific Centre for Materials Science, Hans-Meerwein-Str., 35032 Marburg, Germany; Fax +49-6421-2825785
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Published Online: 2013-08-31 | DOI: https://doi.org/10.1515/epoly.2002.2.1.442

Abstract

Poly(p-xylylene)s (PPX) with aliphatic substituents at the alpha position were synthesized by chemical vapor deposition (CVD) via vapor phase pyrolysis of α-chloro-1,4-xylenes, or by base-induced dehydrohalogenation of α-chloro-1,4- xylenes (Gilch route). These PPXs are soluble under ambient conditions in organic solvents. The glass transition temperature of the tert-butyl substituted PPX is remarkably high. Good thermal stability under nitrogen was observed for the trifluoromethyl substituted PPX. A functionalized compound suitable for polymer analogous reactions is the norbornenyl substituted PPX.

About the article

Published Online: 2013-08-31

Published in Print: 2002-12-01


Citation Information: e-Polymers, Volume 2, Issue 1, 030, ISSN (Online) 1618-7229, ISSN (Print) 2197-4586, DOI: https://doi.org/10.1515/epoly.2002.2.1.442.

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