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Rio, Jose C. / Laine, Christiane / Potthast, Antje / Takano, Toshiyuki / Theliander, Hans


International Journal of the Biology, Chemistry, Physics, and Technology of Wood

Editor-in-Chief: Faix, Oskar

Editorial Board Member: Daniel, Geoffrey / Militz, Holger / Rosenau, Thomas / Salmen, Lennart / Sixta, Herbert / Vuorinen, Tapani / Argyropoulos, Dimitris S. / Balakshin, Yu / Barnett, J. R. / Burgert, Ingo / Evans, Robert / Evtuguin, Dmitry V. / Frazier, Charles E. / Fukushima, Kazuhiko / Gindl-Altmutter, Wolfgang / Glasser, W. G. / Holmbom, Bjarne / Isogai, Akira / Kadla, John F. / Koch, Gerald / Lachenal, Dominique / Mansfield, Shawn D. / Morrell, J.J. / Niemz, Peter / Ragauskas, Arthur J. / Ralph, John / Rice, Robert W. / Salin, Jarl-Gunnar / Schmitt, Uwe / Schultz, Tor P. / Sipilä, Jussi / Tamminen, Tarja / Welling, Johannes / Willför, Stefan / Yoshihara, Hiroshi

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Volume 54, Issue 2 (Feb 2000)


FTIR Characterization of Copper Ethanolamine—Wood Interaction for Wood Preservation

Jun Zhang / D. Pascal Kamdem
Published Online: 2005-06-01 | DOI: https://doi.org/10.1515/HF.2000.020


The interaction of copper ethanolamine (Cu-EA) preservative and wood components was studied by using Fourier transform infrared spectroscopy (FTIR). In Cu-EA treated wood, significant reduction was noticed on the band attributed to carbonyl vibration from carboxylic groups at 1735 ± 5 cm−1 and an increase in band intensity was obtained from carbonyl in carboxylate at 1595 ± 5 cm−1. The same observation was made in Cu-EA treated holocellulose. Cu-EA treated lignin resulted in a reduction in the aromatic ester band at 1710 ± 5 cm−1 and an increase in carbonyl from carboxylate at 1595 ± 5 cm−1. Bands at 1370 cm−1 and 1221 cm−1, assigned to phenolic hydroxyl groups, exhibited a decrease in intensity after the treatment. From these data, it is concluded that Cu-EA interacts with carboxylic groups, phenolic hydroxyl groups and ester groups from lignin to form copper carboxylate and phenolate complexes.

About the article

Published Online: 2005-06-01

Published in Print: 2000-02-29

Citation Information: Holzforschung, ISSN (Print) 0018-3830, DOI: https://doi.org/10.1515/HF.2000.020. Export Citation

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