Cellulose – Hemicelluloses – Lignin – Wood Extractives
Editor-in-Chief: Faix, Oskar / Salmén, Lennart
Editorial Board: Daniel, Geoffrey / Militz, Holger / Rosenau, Thomas / Sixta, Herbert / Vuorinen, Tapani / Argyropoulos, Dimitris S. / Balakshin, Yu / Barnett, J. R. / Burgert, Ingo / Rio, Jose C. / Evans, Robert / Evtuguin, Dmitry V. / Frazier, Charles E. / Fukushima, Kazuhiko / Gindl-Altmutter, Wolfgang / Glasser, W. G. / Holmbom, Bjarne / Isogai, Akira / Kadla, John F. / Koch, Gerald / Lachenal, Dominique / Laine, Christiane / Mansfield, Shawn D. / Morrell, J.J. / Niemz, Peter / Potthast, Antje / Ragauskas, Arthur J. / Ralph, John / Rice, Robert W. / Salin, Jarl-Gunnar / Schmitt, Uwe / Schultz, Tor P. / Sipilä, Jussi / Takano, Toshiyuki / Tamminen, Tarja / Theliander, Hans / Welling, Johannes / Willför, Stefan / Yoshihara, Hiroshi
12 Issues per year
IMPACT FACTOR 2017: 2.079
CiteScore 2017: 1.94
SCImago Journal Rank (SJR) 2017: 0.709
Source Normalized Impact per Paper (SNIP) 2017: 0.979
Effects of Acetylation and Hydrothermal Treatment on Lignin as Revealed by Cellular UV-Spectroscopy in Norway Spruce (Picea abies [L.] Karst.)
The effect of two different wood modification treatments on the lignin of Norway spruce wood was studied by means of cellular UV-spectroscopy. The modification treatments chosen were acetylation using acetic anhydride and a two step hydrothermal treatment. Small cross sectional thin slides from the wood surface were taken and were subsequently analysed using a UV-micro-spectro-photometer. The modified samples were compared with a non-treated control sample. The results revealed changes in the absorption spectra of lignin after both modification treatments. Spectra of the compound middle lamella (CML) of acetylated wood revealed a decrease in the lignin-specific absorption maximum at 280nm, which is considered to be caused by superficial leaching of lignin due to acetylation. The retarding effect of acetylation on UV-degradation of wood is discussed. In hydrothermal-treated wood the 280nm maximum was increased within the S2 layer. This maximum remained almost unchanged in the CML while a lower maximum was observed at about 330nm. Changes in the chromophoric behaviour of lignin are probably caused by de-masking reactions within the S2 layer resulting from hydrolysis of carbohydrates and side chain reactions. Both treatments lead to a severe decrease in absorption at the lower end of the spectrum towards 250nm which is possibly attributed to changes or even splitting of biphenyls.
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