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Wood Research and Technology

Holzforschung

Cellulose – Hemicelluloses – Lignin – Wood Extractives

Editor-in-Chief: Salmén, Lennart

Editorial Board: Daniel, Geoffrey / Militz, Holger / Rosenau, Thomas / Sixta, Herbert / Vuorinen, Tapani / Argyropoulos, Dimitris S. / Balakshin, Yu / Barnett, J. R. / Burgert, Ingo / Rio, Jose C. / Evans, Robert / Evtuguin, Dmitry V. / Frazier, Charles E. / Fukushima, Kazuhiko / Gindl-Altmutter, Wolfgang / Glasser, W. G. / Holmbom, Bjarne / Isogai, Akira / Kadla, John F. / Koch, Gerald / Lachenal, Dominique / Laine, Christiane / Mansfield, Shawn D. / Morrell, J.J. / Niemz, Peter / Potthast, Antje / Ragauskas, Arthur J. / Ralph, John / Rice, Robert W. / Salin, Jarl-Gunnar / Schmitt, Uwe / Schultz, Tor P. / Sipilä, Jussi / Takano, Toshiyuki / Tamminen, Tarja / Theliander, Hans / Welling, Johannes / Willför, Stefan / Yoshihara, Hiroshi


IMPACT FACTOR 2017: 2.079

CiteScore 2017: 1.94

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Volume 71, Issue 6

Issues

NMR determination of sorption isotherms in earlywood and latewood of Douglas fir. Identification of bound water components related to their local environment

Marie Bonnet
  • Laboratoire Navier, UMR 8205, Ecole des Ponts ParisTech, IFSTTAR, CNRS, UPE, Marne-la-Vallée, France
  • Other articles by this author:
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/ Denis Courtier-Murias
  • Laboratoire Navier, UMR 8205, Ecole des Ponts ParisTech, IFSTTAR, CNRS, UPE, Marne-la-Vallée, France
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/ Paméla Faure
  • Laboratoire Navier, UMR 8205, Ecole des Ponts ParisTech, IFSTTAR, CNRS, UPE, Marne-la-Vallée, France
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/ Stéphane Rodts
  • Laboratoire Navier, UMR 8205, Ecole des Ponts ParisTech, IFSTTAR, CNRS, UPE, Marne-la-Vallée, France
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/ Sabine Care
  • Corresponding author
  • Laboratoire Navier, UMR 8205, Ecole des Ponts ParisTech, IFSTTAR, CNRS, UPE, Marne-la-Vallée, France
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Published Online: 2017-03-28 | DOI: https://doi.org/10.1515/hf-2016-0152

Abstract

Earlywood (EW) and latewood (LW) have different hygromechanical behaviors, if subjected to relative humidity (RH) variations. To understand this effect better, the adsorption mechanisms of EW and LW of Douglas fir were studied by 2D 1H NMR relaxometry under conditions of equilibrium moisture content (EMC) at 20°C. Two bound water components were detected with relaxation times T1 and T2 indicating that they are located in distinct environments but these are similar in EW and LW. Sorption isotherms were calculated and analyzed based on the sorption model of Dent. A difference of sorption energy between the two water components is in agreement with their mobility difference observed on T1−T2 correlation spectra. Moreover, for the two bound water components, EW and LW exhibit different sorption isotherms at high RH. This may be attributed to a difference of adsorption capacity. Based on the macrofibril models provided by the literature, the following hypothesis is proposed: bound water components are located in lamellar and lenticular areas, both leading to possible deformations.

Keywords: 2D NMR relaxometry; 2D T1−T2 correlation spectra; earlywood; hemicelluloses; latewood; macrofibril; sorption isotherms

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About the article

Received: 2016-09-15

Accepted: 2017-02-15

Published Online: 2017-03-28

Published in Print: 2017-06-27


Citation Information: Holzforschung, Volume 71, Issue 6, Pages 481–490, ISSN (Online) 1437-434X, ISSN (Print) 0018-3830, DOI: https://doi.org/10.1515/hf-2016-0152.

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