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Wood Research and Technology

Holzforschung

Cellulose – Hemicelluloses – Lignin – Wood Extractives

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Natural durability of subfossil oak: wood chemical composition changes through the ages

Jan Baar
  • Corresponding author
  • Department of Wood Science, Mendel University in Brno, Zemědělská 3, 613 00 Brno, Czech Republic
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/ Zuzana Paschová
  • Department of Wood Science, Mendel University in Brno, Zemědělská 3, 613 00 Brno, Czech Republic
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/ Tamás Hofmann
  • Institute of Chemistry, University of Sopron, Bajcsy-Zsilinszky Street 4, H-9400 Sopron, Hungary
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/ Tomáš Kolář
  • Department of Wood Science, Mendel University in Brno, Zemědělská 3, 613 00 Brno, Czech Republic
  • Global Change Research Institute CAS, Bělidla 986/4a, 603 00 Brno, Czech Republic
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/ Gerald Koch
  • Johann Heinrich von Thünen Institute, Federal Research Institute for Rural Areas, Forestry and Fisheries, Bundesallee 50, 38116 Braunschweig, Germany
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/ Bodo Saake
  • Chemical Wood Technology, University of Hamburg, Haidkrugsweg 1, 22885 Barsbüttel-Willinghusen, Germany
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/ Peter Rademacher
  • Department of Wood Science, Mendel University in Brno, Zemědělská 3, 613 00 Brno, Czech Republic
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Published Online: 2019-08-14 | DOI: https://doi.org/10.1515/hf-2018-0309

Abstract

In recent years, subfossil oak has become increasingly popular, particularly in the manufacture of small wooden products. Due to the long period of its underground preservation, detailed knowledge of its properties is essential to properly use this material. In this study, subfossil oak samples dated to approximately 1000, 2000 and 3000 years BP and recent oak samples were chemically analyzed to determine the contents of extractives, the main wood components, and inorganic elements. The results were then evaluated in light of their natural durability. The mass loss of subfossil oak was 2–3 times lower than that of the recent sample, but the age of the subfossil oak itself had no influence on its durability. The long-term leaching process of water-soluble ellagitannins, together with their hydrolysis and bonding in ferric tannate complexes, were responsible for the decreased durability. The oldest subfossil oak had the lowest amount of phenolic compounds and the highest content of inorganic elements. Optical emission spectrometry proved an increase in inorganic elements 5–7 times higher than recent oak content, with the highest increase found for calcium and iron. Compared to recent oaks, subfossil oaks manifested decreased content of carbohydrates and correspondingly increased lignin content. Our results revealed that subfossil oak cannot be considered a suitable material for exterior use under aerobic conditions.

Keywords: ellagitannins; extractives; inorganic elements; subfossil oak; wood-rotting fungi

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About the article

Received: 2018-12-31

Accepted: 2019-06-27

Published Online: 2019-08-14


Funding Source: European Social Fund

Award identifier / Grant number: CZ.1.07/2.3.00/20.0269

Funding Source: Czech Science Foundation

Award identifier / Grant number: GA18-11004S

Funding Source: Ministry of Education, Youth and Sports of CR within the National Sustainability Program I (NPUI)

Award identifier / Grant number: LO1415

The paper was supported by the European Social Fund and the state budget of the Czech Republic, project “The Establishment of an International Research Team for the Development of New Wood-based Materials”, reg. no. CZ.1.07/2.3.00/20.0269 (funder Id: http://dx.doi.org/10.13039/501100004895) and the Czech Science Foundation project no. GA18-11004S (funder Id: http://dx.doi.org/10.13039/501100001824), Extension of the Czech Millennia-long Oak Tree-ring Width Chronology; and the Ministry of Education, Youth and Sports of CR within the National Sustainability Program I (NPUI), grant no. LO1415 (funder Id: http://dx.doi.org/10.13039/501100001823).


Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

Employment or leadership: None declared.

Honorarium: None declared.


Citation Information: Holzforschung, 20180309, ISSN (Online) 1437-434X, ISSN (Print) 0018-3830, DOI: https://doi.org/10.1515/hf-2018-0309.

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