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High Temperature Materials and Processes

Editor-in-Chief: Fukuyama, Hiroyuki

Editorial Board: Waseda, Yoshio / Fecht, Hans-Jörg / Reddy, Ramana G. / Manna, Indranil / Nakajima, Hideo / Nakamura, Takashi / Okabe, Toru / Ostrovski, Oleg / Pericleous, Koulis / Seetharaman, Seshadri / Straumal, Boris / Suzuki, Shigeru / Tanaka, Toshihiro / Terzieff, Peter / Uda, Satoshi / Urban, Knut / Baron, Michel / Besterci, Michael / Byakova, Alexandra V. / Gao, Wei / Glaeser, Andreas / Gzesik, Z. / Hosson, Jeff / Masanori, Iwase / Jacob, Kallarackel Thomas / Kipouros, Georges / Kuznezov, Fedor

IMPACT FACTOR 2018: 0.427
5-year IMPACT FACTOR: 0.471

CiteScore 2018: 0.58

SCImago Journal Rank (SJR) 2018: 0.231
Source Normalized Impact per Paper (SNIP) 2018: 0.377

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Volume 31, Issue 6


Encapsulation of Erbium(III) and Thulium(III) Nanocomplexes Containing 18- and 20-Membered Dioxa Tetraaza Macryclic Ligands Within the Framework of Zeolite

Mohammad Yousefi / Masoud Salavati-Niasari
Published Online: 2012-12-13 | DOI: https://doi.org/10.1515/htmp-2012-0001


Zeolite framework stabilized erbium(III) and thulium(III) complex nanoparticles was prepared for the first time by using a two step procedure: the ion exchange of Ln3+ (Ln: Er and Tm) with the extra framework Na+ ions in zeolite-Y, the template synthesis of 2,6-diformyl-4-methylphenol with different diamines. Analysis of the data indicated that the Ln(III) complexes has been encapsulated within the nanocavity of zeolite Y and exhibit different property from those of the free complexes, which can arise from distortions caused by steric effects due to the presence of sodium cations, or from interactions with the zeolite matrix.

Keywords: Zeolite; complex nanoparticles; erbium(III); thulium(III); macrocyclic schiff base

About the article

Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P.O. Box. 87317-51167, I.R. Iran

Received: 2012-02-04

Accepted: 2012-02-18

Published Online: 2012-12-13

Published in Print: 2012-12-14

Citation Information: , Volume 31, Issue 6, Pages 733–739, ISSN (Online) 2191-0324, ISSN (Print) 0334-6455, DOI: https://doi.org/10.1515/htmp-2012-0001.

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©[2012] by Walter de Gruyter Berlin Boston.Get Permission

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