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High Temperature Materials and Processes

Editor-in-Chief: Fukuyama, Hiroyuki

Editorial Board: Waseda, Yoshio / Fecht, Hans-Jörg / Reddy, Ramana G. / Manna, Indranil / Nakajima, Hideo / Nakamura, Takashi / Okabe, Toru / Ostrovski, Oleg / Pericleous, Koulis / Seetharaman, Seshadri / Straumal, Boris / Suzuki, Shigeru / Tanaka, Toshihiro / Terzieff, Peter / Uda, Satoshi / Urban, Knut / Baron, Michel / Besterci, Michael / Byakova, Alexandra V. / Gao, Wei / Glaeser, Andreas / Gzesik, Z. / Hosson, Jeff / Masanori, Iwase / Jacob, Kallarackel Thomas / Kipouros, Georges / Kuznezov, Fedor


IMPACT FACTOR 2018: 0.427
5-year IMPACT FACTOR: 0.471

CiteScore 2018: 0.58

SCImago Journal Rank (SJR) 2018: 0.231
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Open Access
Online
ISSN
2191-0324
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Volume 32, Issue 3

Issues

Modeling Activity and Interaction Coefficients of Components of Multicomponent Alloy Melts: An Example of Iron Melt

Ning Zhang / Weiliang Chen / Xingqiu Chen / Xueyong Ding / Guozhi Zhou
  • Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2013-06-15 | DOI: https://doi.org/10.1515/htmp-2012-0123

Abstract

As a popular thermodynamic calculation method for binary alloys, Miedema's model has been applied in many fields. Chou's Model, a new generation of geometric model for ternary and multicomponent alloy systems, overcomes the intrinsic theoretical defects (including symmetric and asymmetric) existing in some original geometric models. Here, by means of combining Miedema's model and Chou's model as well as including the consideration of the excess entropy we attempted to build the new thermodynamic model to evaluate thermodynamic properties of ternary and multicomponent alloying systems in terms of the physical parameters (molar volume, electronegativity, electronic density and melting point) of constituents. Moreover, the activity and interaction coefficients of a wide of components in iron melt have been discussed in details.

Keywords: Miedema's model; Chou's model; ternary alloy; free volume theory; excess entropy

About the article

Received: 2012-08-04

Accepted: 2013-01-04

Published Online: 2013-06-15

Published in Print: 2013-06-14


Citation Information: High Temperature Materials and Processes, Volume 32, Issue 3, Pages 215–221, ISSN (Online) 2191-0324, ISSN (Print) 0334-6455, DOI: https://doi.org/10.1515/htmp-2012-0123.

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©[2013] by Walter de Gruyter Berlin Boston.Get Permission

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