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High Temperature Materials and Processes

Editor-in-Chief: Fukuyama, Hiroyuki

Editorial Board: Waseda, Yoshio / Fecht, Hans-Jörg / Reddy, Ramana G. / Manna, Indranil / Nakajima, Hideo / Nakamura, Takashi / Okabe, Toru / Ostrovski, Oleg / Pericleous, Koulis / Seetharaman, Seshadri / Straumal, Boris / Suzuki, Shigeru / Tanaka, Toshihiro / Terzieff, Peter / Uda, Satoshi / Urban, Knut / Baron, Michel / Besterci, Michael / Byakova, Alexandra V. / Gao, Wei / Glaeser, Andreas / Gzesik, Z. / Hosson, Jeff / Masanori, Iwase / Jacob, Kallarackel Thomas / Kipouros, Georges / Kuznezov, Fedor


IMPACT FACTOR 2018: 0.427
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Open Access
Online
ISSN
2191-0324
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Volume 32, Issue 3

Issues

Thermodynamic Modeling of the CaO-SiO2-M2O (M=K,Na) Systems

Ligang Zhang
  • Corresponding author
  • Freiberg University of Mining and Technology, Centre for Innovation Competence VIRTUHCON, 09596 Freiberg, Germany
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  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Clemens Schmetterer
  • Freiberg University of Mining and Technology, Centre for Innovation Competence VIRTUHCON, 09596 Freiberg, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Patrick J. Masset
Published Online: 2013-06-15 | DOI: https://doi.org/10.1515/htmp-2012-0127

Abstract

The aim of the present study is the CALPHAD modeling of the systems CaO-SiO2-M2O (M=K,Na) based on a careful review of the available literature data – phase diagram and thermodynamics – as well as own experiments. The heat capacities (Cp) of three compounds, CaSiO3, K2Ca2Si2O7 and K8CaSi10O25 (determined using drop calorimetry), were included in the optimization of the ternary phase diagram CaO-SiO2-K2O.

Keywords: thermodynamics; phase diagram; modeling; molten slag

About the article

Received: 2012-08-02

Accepted: 2012-10-29

Published Online: 2013-06-15

Published in Print: 2013-06-14


Citation Information: High Temperature Materials and Processes, Volume 32, Issue 3, Pages 223–228, ISSN (Online) 2191-0324, ISSN (Print) 0334-6455, DOI: https://doi.org/10.1515/htmp-2012-0127.

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©[2013] by Walter de Gruyter Berlin Boston.Get Permission

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