Jump to ContentJump to Main Navigation
Show Summary Details
More options …

International Journal of Chemical Reactor Engineering

Ed. by de Lasa, Hugo / Xu, Charles Chunbao

6 Issues per year


IMPACT FACTOR 2016: 0.623
5-year IMPACT FACTOR: 0.761

CiteScore 2016: 0.58

SCImago Journal Rank (SJR) 2016: 0.224
Source Normalized Impact per Paper (SNIP) 2016: 0.297

Online
ISSN
1542-6580
See all formats and pricing
More options …

Theoretical and Empirical Studies on the Catalytic Partial Oxidation of Methane Promoted by FeY and Fe(piperazine)Y Complexes (Y = Y-zeolite)

Marcio Eduardo Berezuk / Carla C. R. S. Rossi / Nakédia M. F. Carvalho / Pedro Augusto Arroyo / Cláudio Dariva / Adolfo Horn / Lúcio Cardozo-Filho
Published Online: 2011-11-14 | DOI: https://doi.org/10.2202/1542-6580.2381

In this study, we synthesized and characterized zeolite-encapsulated Fe(III) complexes containing piperazine-derived ligands. The catalytic activity of these complexes was tested in the partial oxidation of methane to methanol using O2 as a low-pressure oxidant. Values for methane conversion of up to 1.2% with methanol selectivity of up to 6.7% were obtained. The experimental data were compared with thermodynamic simulation results for the reaction that takes place as a basic principle, the minimization of Gibbs free energy.

Keywords: methane oxidation; encapsulated Fe(III) complexes; ship-in-a-bottle; Gibbs free energy; iron

About the article

Published Online: 2011-11-14


Citation Information: International Journal of Chemical Reactor Engineering, Volume 9, Issue 1, ISSN (Online) 1542-6580, DOI: https://doi.org/10.2202/1542-6580.2381.

Export Citation

©2012 Walter de Gruyter GmbH & Co. KG, Berlin/Boston. Copyright Clearance Center

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Wagner S. Terra, Sarah S. Ferreira, Rafael O. Costa, Luisa L. Mendes, Roberto W.A. Franco, Adailton J. Bortoluzzi, Jackson A.L.C. Resende, Christiane Fernandes, and Adolfo Horn
Inorganica Chimica Acta, 2016, Volume 450, Page 353

Comments (0)

Please log in or register to comment.
Log in