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International Journal of Chemical Reactor Engineering

Ed. by de Lasa, Hugo / Xu, Charles Chunbao

12 Issues per year

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Volume 9, Issue 1


Volume 9 (2011)

Volume 8 (2010)

Volume 7 (2009)

Volume 6 (2008)

Volume 5 (2007)

Volume 4 (2006)

Volume 3 (2005)

Volume 2 (2004)

Volume 1 (2002)

Theoretical and Empirical Studies on the Catalytic Partial Oxidation of Methane Promoted by FeY and Fe(piperazine)Y Complexes (Y = Y-zeolite)

Marcio Eduardo Berezuk / Carla C. R. S. Rossi / Nakédia M. F. Carvalho / Pedro Augusto Arroyo / Cláudio Dariva / Adolfo Horn / Lúcio Cardozo-Filho
Published Online: 2011-11-14 | DOI: https://doi.org/10.2202/1542-6580.2381

In this study, we synthesized and characterized zeolite-encapsulated Fe(III) complexes containing piperazine-derived ligands. The catalytic activity of these complexes was tested in the partial oxidation of methane to methanol using O2 as a low-pressure oxidant. Values for methane conversion of up to 1.2% with methanol selectivity of up to 6.7% were obtained. The experimental data were compared with thermodynamic simulation results for the reaction that takes place as a basic principle, the minimization of Gibbs free energy.

Keywords: methane oxidation; encapsulated Fe(III) complexes; ship-in-a-bottle; Gibbs free energy; iron

About the article

Published Online: 2011-11-14

Citation Information: International Journal of Chemical Reactor Engineering, Volume 9, Issue 1, ISSN (Online) 1542-6580, DOI: https://doi.org/10.2202/1542-6580.2381.

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