International Journal of Chemical Reactor Engineering
Ed. by de Lasa, Hugo / Xu, Charles Chunbao
IMPACT FACTOR 2017: 0.881
5-year IMPACT FACTOR: 0.908
CiteScore 2017: 0.86
SCImago Journal Rank (SJR) 2017: 0.306
Source Normalized Impact per Paper (SNIP) 2017: 0.503
The Influence of Boria and EDTA on the Hydrodesulfurization Activity on CoMoS Supported Catalysts
The hydrodesulfurization of dibenzothiophene (HDS of DBT) in a high pressure batch reactor at 320°C was carried out over CoMo/Al2O3-B2O3 catalysts with different B2O3 contents (4, 10, and 16 wt%). Ethylenediaminetetraacetic acid (EDTA) with different EDTA/Co mole ratios (0.6, 1.2 and 1.8) was used as a chelating ligand during the preparation of CoMo/Al2O3-B2O3. XRD studies, FTIR, TPD of NH3, and BET experiments were used to investigate the catalyst samples. The results showed that the catalyst using the support with 4 wt% B2O3 and an EDTA/Co mole ratio of 1.2 had a hydrodesulfurization activity (in pseudo first order kinetic constant basis) value of ~2.96 times higher than that of the simple CoMo/Al2O3 catalyst.
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