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International Journal of Chemical Reactor Engineering

Ed. by de Lasa, Hugo / Xu, Charles Chunbao

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Volume 13, Issue 3

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A Study on the Production of Isophthalic Acid from M-xylene under the Catalysis of Cobalt and H3PW12O40/Carbon Modified by HNO3 Solution

Zhi-hao Wang
  • State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Meilong Road 300, Shanghai 200237, P. R. China
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/ Zhi-lin Yang
  • State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Meilong Road 300, Shanghai 200237, P. R. China
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/ Shi-ming Wu
  • State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Meilong Road 300, Shanghai 200237, P. R. China
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/ Xiang-li Long
  • Corresponding author
  • State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Meilong Road 300, Shanghai 200237, P. R. China
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Published Online: 2015-08-04 | DOI: https://doi.org/10.1515/ijcre-2015-0032

Abstract

The oxidation of m-xylene(MX) to isophthalic acid(IPA) catalyzed by phosphotungstic acid(HPW) supported on modified activated carbon was investigated. The activated carbon loading with HPW is modified by HNO3 solution to ameliorate its catalytic capability in the oxidation of MX to IPA. Experiments have been carried out to study the effects of modification conditions, such as HNO3 concentration, impregnation time, impregnation temperature, activation temperature and activation time, on the catalytic performance of activated carbon. The experimental results demonstrate that the carbon sample impregnated in 10%(vol) HNO3 solution at 45°C for 8 h followed by calcined at 700°C for 4 h has the best catalytic capability. The characterization results imply that the specific surface area and micropores of the carbon samples decrease after being treated with HNO3 solution. But the acidic functional groups on the activated carbon surface increase, which play a vital role in improving the catalytic ability of the HPW/C catalyst in the oxidization of m-xylene to IPA.

Keywords: phosphotungstic acid; m-xylene; isophthalic acid; activated carbon; catalytic oxidation

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About the article

Published Online: 2015-08-04

Published in Print: 2015-09-01


Funding: The present work is supported by the NSFC (No. 21176081).


Citation Information: International Journal of Chemical Reactor Engineering, Volume 13, Issue 3, Pages 413–425, ISSN (Online) 1542-6580, ISSN (Print) 2194-5748, DOI: https://doi.org/10.1515/ijcre-2015-0032.

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