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International Journal of Chemical Reactor Engineering

Ed. by de Lasa, Hugo / Xu, Charles Chunbao

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Effect of Natural and Artificial Light on Fe(III) Organic Complexes Photolysis: Case of Fe (III)-Malonate and Fe(III)-Malate

Besma Anfal Dekkiche
  • Laboratoire des Sciences et Technologies de l’Environnement, Université Frères Mentouri, Constantine 1, Algeria
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/ Nassira Seraghni
  • Laboratoire des Sciences et Technologies de l’Environnement, Université Frères Mentouri, Constantine 1, Algeria
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/ Nadra Debbache
  • Corresponding author
  • Laboratoire des Sciences et Technologies de l’Environnement, Université Frères Mentouri, Constantine 1, Algeria
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/ Imane Ghoul
  • Laboratoire des Sciences et Technologies de l’Environnement, Université Frères Mentouri, Constantine 1, Algeria
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/ Tahar Sehili
  • Laboratoire des Sciences et Technologies de l’Environnement, Université Frères Mentouri, Constantine 1, Algeria
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Published Online: 2018-10-05 | DOI: https://doi.org/10.1515/ijcre-2018-0106

Abstract

The photolysis of iron(III) organic complexes in the presence of natural and simulated light was a concern for the role it plays within the environment in terms of producing hydroxyl radicals able to degrade organic products. In the present work, the study focused on two iron(III) organic complexes. The characterization of these complexes by spectrometry allowed to show their stability in environment with a stability constant equal to Log β = 13.13 for the complex Fe(III)-malonate, and Log β = 20.85 for the Fe(III)-malate complex. Photolysis of these complexes was carried out using a lamp at 365 nm at different pHs, and followed by several assay Fe(II), H2O2 and •OH. The complexes present different photo-reactivities, in the case of Fe(III)-malate, the photolysis is favored by the Fenton process and generates hydroxyl radicals, contrarily to Fe(III)-malonate photolysis which generates an oxidizing •CH2COOH radical without formation of H2O2 nor of •OH. The presence of oxygen and the addition of isopropanol and chloroform show different effects on the complex photolysis. Complexes mineralization at natural irradiation was also studied using chemical oxygen demand (COD).

Keywords: Fe(III)-malate; Fe(III)-malonate; photolysis; sunlight

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About the article

Received: 2018-04-20

Accepted: 2018-09-22

Revised: 2018-07-31

Published Online: 2018-10-05


Citation Information: International Journal of Chemical Reactor Engineering, 20180106, ISSN (Online) 1542-6580, DOI: https://doi.org/10.1515/ijcre-2018-0106.

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