Journal of Non-Equilibrium Thermodynamics
Founded by Keller, Jürgen U.
Editor-in-Chief: Hoffmann, Karl Heinz
Managing Editor: Prehl, Janett / Schwalbe, Karsten
Ed. by Michaelides, Efstathios E. / Rubi, J. Miguel
Editorial Board Member: Ahlborn, Boye / Andresen, Bjarne / Badescu, Viorel / Bedeaux, Dick / Bejan, Adrian / Brüggemann, Dieter / Buchholz, Rainer / Cimmelli, Vito Antonio / Dinkelacker, Friedrich / Do, Duong / Fox, Ronald F. / Groll, Manfred / Gross, Joachim / Jou Mirabent, David / Kabelac, S. / Kalliadasis, Serafim / Kjelstrup, S. / Kizilova, Natalya / Kollmann, W. / Lebon, Georgy / Maugin, G. A. / Muschik, Wolfgang / Papenfuss, Christina / Raffa, Robert B. / Ricard, Jacques / Scholl, Stephan / Sieniutycz, Stanislaw / Stark, Holger / Steinchen, Annie / Van, Peter / Velarde, M.G. / Verhas, Jozsef / Stockar, Urs / Winter, Roland / Zaman, Muhammad
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GENERIC Compliance of a Temporary Network Model with Sliplinks, Chain-Length Fluctuations, Segment-Connectivity and Constraint Release
Citation Information: Journal of Non-Equilibrium Thermodynamics. Volume 28, Issue 2, Pages 179–188, ISSN (Print) 0340-0204, DOI: 10.1515/JNETDY.2003.010, June 2005
- Published Online:
It is shown that a recently proposed sliplink theory for polymer melts is consistent with the two-generator, non-equilibrium thermodynamics formalism, GENERIC. The model was previously developed using the free energy as a generator for the dynamics. Its primary novelty is that it uses the monomeric density as a dynamic variable instead of as a parameter. By placing it in the GENERIC framework, I also derive an appropriate energy equation necessary for performing non-isothermal flow calculations. Using the algorithm already proposed and the results given here, it is possible to simulate the complete non-isothermal flow of linear, entangled polymeric fluids in complex geometries.
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