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Latvian Journal of Chemistry

The Journal of Riga Technical University

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Decarboxylative Allylation of Ketone Enolates with Rh, Ir, and Mo

E. Dunn
  • 2010 Malott Hall, 1251 Wescoe Hall Dr., Lawrence, KS USA
/ J. Tunge
  • 2010 Malott Hall, 1251 Wescoe Hall Dr., Lawrence, KS USA
Published Online: 2012-07-16 | DOI: https://doi.org/10.2478/v10161-012-0007-x

Decarboxylative Allylation of Ketone Enolates with Rh, Ir, and Mo

A variety of catalysts were investigated for their ability to impart branched regioselectivity in decarboxylative allylation reactions. While catalysts based on Mo, Rh, and Ir were active catalysts, their regio-selectivities were low and the reactions required an equivalent of base for efficient coupling. Alternatively, a ruthenium-based catalyst was identi-fied that operates under neutral conditions and gives high branched selectivity in decarboxylative allylations.

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Published Online: 2012-07-16

Published in Print: 2012-01-01



Citation Information: Latvian Journal of Chemistry, ISSN (Print) 0868-8249, DOI: https://doi.org/10.2478/v10161-012-0007-x. Export Citation

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