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Main Group Metal Chemistry

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Crystal structure of C2O4 (SnPh3·dimethylformamide)2

Ndongo Gueye1 / 1 / Kieran C. Molloy2 / Gabrielle Kociok-Köhn2

1Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal

2Department of Chemistry, University of Bath, Claverton Down, Bath, BA27AY, UK

Corresponding author

Citation Information: Main Group Metal Chemistry. Volume 34, Issue 1-2, Pages 3–4, ISSN (Online) 2191-0219, ISSN (Print) 0792-1241, DOI: 10.1515/mgmc.2011.008, September 2011

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The structure of C2O4(SnPh3)2. 2dimethylformamide (DMF) has been determined by X-ray. It consists of monomers containing SnPh3residue trans coordinated by DMF, with the environment around the tin centre being trigonal bipyramidal.

Keywords: bidentate oxalate; tin (IV) in a trigonal bipyramidal environment; X-ray crystallography

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