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Geochemical features of fossil fuel contaminants found in urban wastes (Siemianowice Śląskie, Poland)

Anna Wojtoń
  • Faculty of Earth Sciences, University of Silesia, 60 Będzińska Street, 42-700 Sosnowiec, Poland
/ Monika Fabiańska
  • Faculty of Earth Sciences, University of Silesia, 60 Będzińska Street, 42-700 Sosnowiec, Poland
Published Online: 2012-07-04 | DOI: https://doi.org/10.2478/v10002-011-0003-x

Geochemical features of fossil fuel contaminants found in urban wastes (Siemianowice Śląskie, Poland)

In sludge samples collected in the "Centrum" wastewater treatment plant in Siemianowice Śląskie, Poland, the composition of aliphatic- and aromatic hydrocarbons and polar compound fractions were investigated by gas chromatography-mass spectrometry (GC-MS). Samples collected in accordance with Polish standards were extracted, the extracts were separated into fractions with preparative thin layer chromatography (TLC), which next were investigated by GC-MS. The following compound groups of the geochemical origin were identified: n-alkanes in the range of n-C14 to n-C.39, acyclic isoprenoids (mainly pristane and phytane), steranes, tri- and pentacyclic triterpanes. Based on the distribution of biomarkers and their parameters, it was established that the dominant component of extractable organic matter in sluge is petroleum material of an unspecified origin. Its geochemical features indicate that its most likely source was crude oil (or its products) of a relatively high degree of thermal maturity (catagenic stage of thermal evolution corresponding to vitrinite reflectance 0.7-0.8%). Aromatic hydrocarbons probably originated from petroleum also, though some of them can be attributed to the products of combustion or to sources such as bituminous coals, the ash from coal/biofuel combustion or coal wastes stored nearby.

Keywords: fossil fuel biomarkers; gas chromatography-mass spectrometry; wastewater treatment

  • Barthlott, W., Neinhuis, C., Cutler, D., Ditsch, F., Meusel, I., Theisen, I., & Wilhelmi, H. (1998). Classification and terminology of plants epicuticular waxes. Botanical Journal of the Linnean Society, 126, 237-260. DOI: 10.1111/j.1095-8339.1998.tb02529.x. [Crossref]

  • Berset, J.D., & Holzer, R. (1999). Quantitative determination of polycyclic aromatic hydrocarbons, polychlorinated biphenyls and organochlorine pesticides in sewage sludges using supercritical fluid extraction and mass spectrometric detection. Journal of Chromatography A, 852, 545-558. DOI: 10.1016/S0021-9673(99)00641-X. [Crossref]

  • Bodzek, D., & Janoszka, B. (1999). Comparison of polycyclic aromatic compounds and heavy metals contents in sewage sludges from industrialized and non-industrialized region. Water, Air, Soil Pollution, 111, 359-369. DOI: 10.1023/A:1005066327712. [Crossref]

  • Bray, E.E., & Evans, E.D. (1961). Distribution of n-paraffin as a clue to recognition of source beds. Geochimica et Cosmochimica Acta, 22, 2-15. DOI: 10.1016/0016-7037(61)90069-2. [Crossref]

  • Didyk, B.M., Simoneit, B-T., Brassell, S.C., & Eglinton, G. (1978). Organic geochemical indicators of paleoenvironmental conditions of sedimentation. Nature, 272, 217-222.

  • Dong, J-Z., Vorking, W.P., & Lee, M.L. (1993). Origin of long-chain alkylcyclohexanes and alkylbenzenes in a coal-bed wax. Geochimica et Cosmochimica Acta, 57, 837-849.

  • Durand, C., Ruban, V., Ambles, A., & Oudot, J. (2004). Characterization of the organic matter of sludge: determination of lipids, hydrocarbons and PAHs from road retention/infiltration ponds in France. Environmental Pollution, 132, 375-384. DOI: 10.1016/j.envpol.2004.05.038. [Crossref]

  • Eglinton, G., & Hamilton, R.J. (1967). Leaf epicuticular waxes. Science, 156, 1322-1335. DOI: 10.1126/science.156.3780.1322. [Crossref]

  • Eriksson, E., Christensen, N., Schmidt, J.E., & Ledin, A. (2008). Potential priority pollutants in sewage sludge. Desalination, 226, 371-388. DOI:10.1016/j.desal.0000.00.000. [Web of Science] [Crossref]

  • Hartmann, L. (1996). Biologiczne oczyszczanie ścieków. Warszawa: Wydawnictwo Instalator Polski.

  • Huang, W.-Y., & Meinschein, W.G. (1979). Sterols as ecological indicators. Geochimica et Cosmochimica Acta, 43, 739-745. DOI: 10.1016/0016-7037(79)90257-6. [Crossref]

  • International Flavors & Fragrances (2007) Galaxolide® 50 DPG. 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran. Retrievied April 19, 2011, from http://www.iff.com/Ingredients.nsf/0/DFED00F87A7ABAE385256D650044ECD6

  • Kowal, A.L. (1997). Odnowa wody: podstawy teoretyczne procesów (2nd ed., corrected). Wrocław: Oficyna Wydawnicza Politechniki Wrocławskiej.

  • Lewis, M.D., Kleinkopf, G.E., & Shetty, K.K. (1997). Dimethylnaphthalene and diisopropylnaphthalene for potato sprout control in storage: 1. Application methodology and efficacy. American Journal of Potato Research, 74, 183-197. DOI: 10.1007/BF02851597. [Crossref]

  • Leythauser, D., Schwartzkopf Th., (1985). The pristane/n-heptadecane ratio as an indicator for recognition of hydrocarbon migration effects. Organic Geochemistry 10, 191-197. DOI: 10.1016/0146-6380(86)90022-7 [Crossref]

  • Marchal, R., Penet, S., Solano-Serena, F., & Vandecasteele, J.P. (2003). Gasoline and diesel oil biodegradation. Oil & Gas Science and Technology - Rev. IFP 58, 441-448. DOI: 10.2516/ogst:2003027. [Crossref]

  • Miksch, K., & Sikora, J. (2010). Biotechnologia ścieków. Warszawa: Wydawnictwo Naukowe PWN.

  • Noble, R.A., Aleksander, R., Kagi, R.I., & Knox, J. (1986). Identification of some diterpenoid hydrocarbons in petroleum. Organic Chemistry 10, 825-829. DOI: 10.1016/S01 46-6380(86)80019-5. [Crossref]

  • Oil Chem Technologies (2010). Anionic surfactants. New Arylalkyl Sulfonates (AASA). Retrieved April 19, 2011, from http://www.oil-chem.com/anionic.htm

  • Otto, A., & Wilde, V. (2001). Sesqui-, di-, and triterpenoids as chemosystematic markers in extant conifers: a review. Botanical Review 67, 141-238. DOI: 10.1007/BF02858076. [Crossref]

  • Palmer, S.E. (1993). Effect of Biodegradation and Water Washing on Crude Oil Composition, in Organic Geochemistry, Principles and Applications. In M.H. Engel & S.A. Macko (Eds.), New York: Plenum Press.

  • Pawelczyk-Szpilowa, M. (1980). Ćwiczenia z mikrobiologii wody i ścieków. Warszawa: Wydawnictwo Naukowe PWN.

  • Peters, K.E., Walters, C.C., & Moldowan, J.M. (2005). The Biomarker Guide (2nd ed.). Cambridge, Cambridge University Press.

  • Polski Komitet Normalizacyjny (National Standards Body in Poland). (1988). Woda i ścieki - Ogólne zasady pobierania próbek do badań fizycznych, chemicznych i biologicznych - Utrwalanie i przechowywanie próbek (Polish Standard: Water and sewage - General principles of sampling for physical, chemical and biological analyses - Sample preservation and storage). PN-C-04632-04:1988. Warszawa.

  • Radke, M., Welte, D.H. & Willsch, H. (1986). Maturity parameters based on aromatic hydrocarbons: influence of organic matter type. Organic Geochemistry 10, 51-63. DOI: 10.1016/0146-6380(86)90008-2. [Crossref]

  • Scheffler, K. (2004). Reconstruction of sedimentary environment and climate conditions by multi-geochemical investigations of Late Palaeozoic glacial to postglacial sedimentary sequences from SW-Gondwana. Dissertation zur Erlangung des Doktorgrades der Mathematisch-Naturwissenschaftlichen Fakultät der Rheinischen Fredrich-Wilhelms-Univeristät, Bonn http://deposit.ddb.de/

  • Scott, M.J., & Jones, M.N. (2000). The biodegradation of surfactants in the environment. Biochimica et Biophysica Acta, 1508, 235-251. DOI:10.1016/S0304-4157(00)00013-7. [Crossref]

  • Seifert, W.K. & Moldowan, J.M. (1980). The effect of thermal stress on source-rock quality as measured by hopane stereochemistry. Physics and Chemistry of the Earth 12, 229-237. DOI: 10.1016/0079-1946(79)90107-1. [Crossref]

  • Stevens, J.L., Northcott, G.L., Stern, G.A., Tomy, T.G., & Jones, K.C. (2003). PAHs, PCBs, PCNs Organochlorine Pesticides, Synthetic Musks, and Polychlorinated n-Alkanes in U.K. Sewage Sludge: Survey Results and Implications. Environment Science and Technology, 37, 462-467. DOI: 10.1021/es020161y. [Crossref]

  • Tissot, B.P., & Welte, D.H. (1984). Petroleum formation and occurrence. Berlin: Springer-Verlag.

  • Wang, Z., & Fingas, M. (1999). Oil spill identification. Journal of Chromatography A, 843, 369-441. DOI: doi:10.1016/S0021-9673(99)00120-X. [Crossref]

  • Wiley, J. (2000). The Wiley/NBS Registry of Mass Spectral Data. New York: J Wiley and Sons.

  • Zhang, K., Noonan, G.O., & Begley, T.H. (2008). Determination of 2,6-diisopropylnaphthalene (DIPN) and n-dibutylphthalate (DBP) in food and paper packaging materials from US marketplaces. Food Additives and Contaminants, 25(11), 1416-1423. DOI: 10.1080/02652030802163380. [Web of Science] [Crossref]

About the article

Published Online: 2012-07-04

Published in Print: 2011-01-01

Citation Information: Mineralogia, ISSN (Online) 1899-8526, ISSN (Print) 1899-8291, DOI: https://doi.org/10.2478/v10002-011-0003-x. Export Citation

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