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Plasmonic hot carrier dynamics in solid-state and chemical systems for energy conversion

Prineha Narang
  • Joint Center for Artificial Photosynthesis, California Institute of Technology, Pasadena CA 91125 USA
  • Thomas J. Watson Laboratories of Applied Physics, California Institute of Technology, Pasadena CA 91125 USA
/ Ravishankar Sundararaman
  • Joint Center for Artificial Photosynthesis, California Institute of Technology, Pasadena CA 91125 USA
/ Harry A. Atwater
  • Joint Center for Artificial Photosynthesis, California Institute of Technology, Pasadena CA 91125 USA
  • Thomas J. Watson Laboratories of Applied Physics, California Institute of Technology, Pasadena CA 91125 USA
Published Online: 2016-06-11 | DOI: https://doi.org/10.1515/nanoph-2016-0007

Abstract

Surface plasmons provide a pathway to efficiently absorb and confine light in metallic nanostructures, thereby bridging photonics to the nano scale. The decay of surface plasmons generates energetic ‘hot’ carriers, which can drive chemical reactions or be injected into semiconductors for nano-scale photochemical or photovoltaic energy conversion. Novel plasmonic hot carrier devices and architectures continue to be demonstrated, but the complexity of the underlying processes make a complete microscopic understanding of all the mechanisms and design considerations for such devices extremely challenging.Here,we review the theoretical and computational efforts to understand and model plasmonic hot carrier devices.We split the problem into three steps: hot carrier generation, transport and collection, and review theoretical approaches with the appropriate level of detail for each step along with their predictions.We identify the key advances necessary to complete the microscopic mechanistic picture and facilitate the design of the next generation of devices and materials for plasmonic energy conversion.

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About the article

Received: 2015-10-22

Accepted: 2016-01-14

Published Online: 2016-06-11

Published in Print: 2016-06-01



Citation Information: Nanophotonics, ISSN (Online) 2192-8614, ISSN (Print) 2192-8606, DOI: https://doi.org/10.1515/nanoph-2016-0007. Export Citation

© 2016. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License. (CC BY-NC-ND 4.0)

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