Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Nukleonika

The Journal of Instytut Chemii i Techniki Jadrowej

4 Issues per year


IMPACT FACTOR 2016: 0.760

CiteScore 2016: 0.55

SCImago Journal Rank (SJR) 2015: 0.205
Source Normalized Impact per Paper (SNIP) 2015: 0.461

Open Access
Online
ISSN
0029-5922
See all formats and pricing
More options …

Crystal structure and Mössbauer study of FeAl2O4

Ilona Jastrzębska
  • Department of Ceramics and Refractories, Faculty of Materials Science and Ceramics, AGH – University of Science and Technology, 30 Mickiewicza Ave., 30-059 Kraków, Poland
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jacek Szczerba
  • Department of Ceramics and Refractories, Faculty of Materials Science and Ceramics, AGH – University of Science and Technology, 30 Mickiewicza Ave., 30-059 Kraków, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Paweł Stoch
  • Department of Ceramics and Refractories, Faculty of Materials Science and Ceramics, AGH – University of Science and Technology, 30 Mickiewicza Ave., 30-059 Kraków, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Artur Błachowski
  • Mössbauer Spectroscopy Division, Institute of Physics, Pedagogical University, 2 Podchorążych Str., 30-084 Kraków, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Krzysztof Ruebenbauer
  • Mössbauer Spectroscopy Division, Institute of Physics, Pedagogical University, 2 Podchorążych Str., 30-084 Kraków, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Ryszard Prorok
  • Department of Ceramics and Refractories, Faculty of Materials Science and Ceramics, AGH – University of Science and Technology, 30 Mickiewicza Ave., 30-059 Kraków, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Edyta Śnieżek
  • Department of Ceramics and Refractories, Faculty of Materials Science and Ceramics, AGH – University of Science and Technology, 30 Mickiewicza Ave., 30-059 Kraków, Poland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2015-03-12 | DOI: https://doi.org/10.1515/nuka-2015-0012

Abstract

In this work the synthesis of hercynite from Fe2O3 and Al2O3 powders was carried out by arc-melting method under the protective argon atmosphere. The obtained material was characterized with the use of powder X-ray diffractometry (XRD) and Mössbauer spectroscopy (MS). A Mössbauer effect in hercynite obtained by the arc-melting method indicated the cations distribution in the spinel structure among the tetrahedral and octahedral interstices. The presence of Fe2+ ions was detected in both tetrahedral and octahedral sites while Fe3+ ions occupied only the octahedral interstices. The approximate formula of the obtained iron-aluminate spinel was as follows (Fe2+0.77Al3+0.23) (Fe3+0.07Fe2+0.05Al0.88)2O4.

Keywords: FeAl2O4; hercynite; Mössbauer spectroscopy; spinel

References

  • 1. Hill, H. J., Craig, J. R., & Gibbs, G. V. (1979). Systematics of the spinel structure type. Phys. Chem. Minerals, 4, 317–339.CrossrefGoogle Scholar

  • 2. Dormann, J. L., Seqqat, M., Fiorani, D., Nogues, M., Soubeyroux, J. L., Bhargava, S. C., & Renaudin, P. (1990). Mössbauer studies of FeAl2O4 and FeIn2S4 spin glass spinels. Hyperfine Interact., 54, 503–508. DOI: 10.1007/s10751-004-7332-8.CrossrefGoogle Scholar

  • 3. Russo, U., Carbonin, S., & Giusta, A. D. (1996). Mössbauer spectral studies of natural substituted spinels. In G. J. Long & F. Grandjean (Eds.), Mössbauer spectroscopy applied to magnetism and material science (Vol. 2, Chapter 9). New York: Plenum Press.Google Scholar

  • 4. Sickafus, K. E., Wills, J. M., & Grimes, N. W. (1999). Structure of spinel. J. Am. Ceram. Soc., 82(12), 3279–3292. DOI: 10.1111/j.1151-2916.1999.tb02241.x.CrossrefGoogle Scholar

  • 5. Roisnel, T., & Rodriguez-Carvajal, J. (2000). Win-PLOTR: a Windows tool for powder diffraction patterns analysis. In Materials Science Forum: Proceedings of the 7th European Powder Diffraction Conference, 20–23 May 2000, Barcelona, Spain (EPDIC 7) (pp. 118–123).Google Scholar

  • 6. Rancourt, D. G., & Ping, J. Y. (1991). Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mössbauer spectroscopy. Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 58(1), 85–97.CrossrefGoogle Scholar

  • 7. Lenaz, D., & Skokby, H. (2013). Structural changes in the FeAl2O4-FeCr2O4 solid solutions series and their consequences on natural Cr-bearing spinels, Phys. Chem. Miner., 40(7), 587–595. DOI: 10.1007/s00269-013-0595-3.Web of ScienceCrossrefGoogle Scholar

  • 8. Yagnik, C. M., & Mathur, H. B. (1968). A Mössbauer and X-ray diffraction study on the cation distribution in FeAl2O4, J. Phys. C, 2(1), 469–472. DOI: 10.1088/0022-3719/1/2/320.CrossrefGoogle Scholar

  • 9. Andreozzi, G. B., Baldi, G., Bernardini, G. P., Benedetto, F., & Romanelli, M. (2004). 57Fe Mössbauer and electronic spectroscopy study on a new synthetic hercynite-based pigment, J. Eur. Ceram. Soc., 24, 821–824. DOI: 10.1016/S0955-2219(03)00329-7.CrossrefGoogle Scholar

About the article

Received: 2014-06-18

Accepted: 2014-11-02

Published Online: 2015-03-12

Published in Print: 2015-03-01


Citation Information: Nukleonika, Volume 60, Issue 1, Pages 47–49, ISSN (Online) 0029-5922, DOI: https://doi.org/10.1515/nuka-2015-0012.

Export Citation

© Ilona Jastrzębska, Jacek Szczerba, Paweł Stoch, Artur Błachowski, Krzysztof Ruebenbauer, Ryszard Prorok, Edyta Śnieżek. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Silviana Onisei, Alexios P. Douvalis, Annelies Malfliet, Arne Peys, and Yiannis Pontikes
Journal of the American Ceramic Society, 2018
[2]
M. Yaseen, Q. Mahmood, Shahid M. Ramay, I. Ali, M. Y. Naz, and Asif Mahmood
Journal of Superconductivity and Novel Magnetism, 2017
[3]
Yanyan Zhu, Weiwei Liu, Xueyan Sun, Xiaoxun Ma, Yu Kang, Xiaodong Wang, and Junhu Wang
AIChE Journal, 2017
[4]
Ilona Jastrzębska, Wiktor Bodnar, Kerstin Witte, Eberhard Burkel, Paweł Stoch, and Jacek Szczerba
Nukleonika, 2017, Volume 62, Number 2
[5]
B.E. Monárrez-Cordero, P. Amézaga-Madrid, L. Fuentes-Cobas, M.E. Montero-Cabrera, and M. Miki-Yoshida
Journal of Alloys and Compounds, 2017, Volume 718, Page 414
[6]
M. Kamran, A. Ullah, S. Rahman, A. Tahir, K. Nadeem, M. Anis ur Rehman, and S. Hussain
Journal of Magnetism and Magnetic Materials, 2017, Volume 433, Page 178
[7]
Mirko Congiu, Maria L. De Marco, Matteo Bonomo, Oswaldo Nunes-Neto, Danilo Dini, and Carlos F.O. Graeff
Journal of Nanoparticle Research, 2017, Volume 19, Number 1
[8]
Jiankang Wang, Zhongping Yao, Min Yang, Yajing Wang, Qixing Xia, and Zhaohua Jiang
Environmental Science and Pollution Research, 2016, Volume 23, Number 15, Page 14927
[9]
M.A. Laguna-Marco, J. Sánchez-Marcos, N. Menéndez, J. Chaboy, E. Salas-Colera, and C. Prieto
Materials & Design, 2016, Volume 93, Page 388

Comments (0)

Please log in or register to comment.
Log in