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Organic Photonics and Photovoltaics

Editor-in-Chief: Facchetti, Antonio

Ed. by Ponomarenko, Sergei

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2299-3177
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Photoconductive and nonlinear optical properties of composites based on metallophthalocyanines

A. V. Vannikov / A. D. Grishina / Yu. G. Gorbunova / A. Yu. Tsivadze
Published Online: 2015-08-03 | DOI: https://doi.org/10.1515/oph-2015-0008

Abstract

The photoconductive, photorefractive and nonlinear optical properties of composites from polyvinylcarbazole or aromatic polyimide containing supramolecular ensembles of (tetra-15-crown-5) - phthalocyaninato gallium, indium, - phthalocyaninateacetato yttrium, - phthalocyaninato ruthenium with axially coordinated pyrazine molecules were investigated at 633, 1030 and 1064nmusing continuous and pulsed lasers. Supramolecular ensembles (SE) were prepared through dissolution of molecular metallophthalocyanines in tetrachloroethane (TCE) and subsequent treatment via three cycles of heating to 90∘C and slow cooling to room temperature. The zscan method in femtosecond and nanosecond regimeswas used for measuring nonlinear optical properties phthalocyaninato indium and yttrium in TCE solutions and polymer films. It was established that effect of heavy metallic atom is basic factor which determines the quantum yield, photorefractive amplification of laser object beam, dielectric susceptibility of third order and nonlinear optical properties of metallophthalocyanines.

Keywords: Photoconductive; nonlinear optical properties of metallophthalocyanines

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About the article

Received: 2014-08-01

Accepted: 2015-03-27

Published Online: 2015-08-03


Citation Information: Organic Photonics and Photovoltaics, ISSN (Online) 2299-3177, DOI: https://doi.org/10.1515/oph-2015-0008.

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©2015 A. V. Vannikov et al.. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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[1]
A. D. Grishina, T. V. Krivenko, V. V. Savel’ev, and A. V. Vannikov
Protection of Metals and Physical Chemistry of Surfaces, 2016, Volume 52, Number 5, Page 797

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