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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Stohner, Jürgen


IMPACT FACTOR 2017: 5.294

CiteScore 2017: 3.42

SCImago Journal Rank (SJR) 2017: 1.212
Source Normalized Impact per Paper (SNIP) 2017: 1.546

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1365-3075
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Volume 72, Issue 1-2

Issues

Silica-coated metals and semiconductors. Stabilization and nanostructuring

Marta Alejandro-Arellano
  • Corresponding author
  • Departamento de Química Física, Universidade de Vigo, E-36200, Vigo, Spain
  • Other articles by this author:
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/ Thearith Ung
  • Corresponding author
  • Departamento de Química Física, Universidade de Vigo, E-36200, Vigo, Spain
  • Other articles by this author:
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/ Álvaro Blanco
  • Corresponding author
  • Departamento de Química Física, Universidade de Vigo, E-36200, Vigo, Spain
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/ Paul Mulvaney
  • Corresponding author
  • Departamento de Química Física, Universidade de Vigo, E-36200, Vigo, Spain
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/ Luis M. Liz-Marzán
  • Corresponding author
  • Departamento de Química Física, Universidade de Vigo, E-36200, Vigo, Spain
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  • De Gruyter OnlineGoogle Scholar
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200072010257

We present in this paper the use of silica-coating for nanostructuring metal and semiconductor nanoparticles. The basic concept is the strict tailoring of the interparticle spacing through the thickness of the silica shell. Three different experiments are presented that exemplify this concept. The first example consists of the preparation of thin films using the layer-by-layer self-assembly of gold nanoparticles, either uncoated or coated with thin silica shells. The observed optical effects are interpreted using effective medium theory. The second and third experiments are related to the preparation of three-dimensional nanostructures, either as concentrated dispersions of thickly coated Au or CdS nanoparticles, or as opals prepared from such core-shell nanoparticles. Within these crystalline solids, intercore distance is again dictated by the thickness of the silica shells.

Conference

Workshop on Advanced Material (WAM1: Nanostructured Systems), Workshop on Advanced Materials, WAM, Advanced Materials, Hong Kong, China, 1999-07-14–1999-07-18

About the article

Published Online: 2009-01-01

Published in Print: 2000-01-01


Citation Information: Pure and Applied Chemistry, Volume 72, Issue 1-2, Pages 257–267, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200072010257.

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