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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen

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1365-3075
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Volume 72, Issue 7 (Jan 2000)

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Solid acids and their use as environmentally friendly catalysts in organic synthesis

Karen Wilson
  • Corresponding author
  • Green Chemistry Group, Department of Chemistry, University of York, Heslington, York YO10 5DD, UK
/ James H. Clark
  • Corresponding author
  • Green Chemistry Group, Department of Chemistry, University of York, Heslington, York YO10 5DD, UK
Published Online: 2009-01-01 | DOI: https://doi.org/10.1351/pac200072071313

Tightening environmental legislation is driving the fine and speciality chemicals industries to consider alternative processes that avoid the use of conventional mineral acids. The use of heterogeneous catalysts in these processes would vastly simplify catalyst removal, minimizing the amount of waste formed. However, diffusion limitation of liquids within porous solids dictates that effective solid acids for liquid-phase reactions require the use of mesoporous materials <20_100Å. Recent developments in materials chemistry has led to the discovery of a family of ordered mesoporous silicas which opens up new possibilities for preparing solid-acid catalysts for liquid-phase reactions. This review concentrates on recent developments in the synthesis of new mesoporous solid acids for liquid-phase organic synthesis.

About the article

Published Online: 2009-01-01

Published in Print: 2000-01-01


Citation Information: Pure and Applied Chemistry, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac200072071313. Export Citation

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